A 3D coordination framework with an unusual 1D inorganic chain based on the Lindqvist-type [Hg6Br19]7- anion

被引：5
作者：
Weng, Yan-Qin [1 ]
Cao, Man-Li [2 ]
Ye, Bao-Hui [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
[2] Guangdong Univ Educ, Dept Chem, Guangzhou 510303, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期
关键词：
Lindqvist-type anion; 1D Inorganic chain; Mercury ion cluster; Bromide ion cluster; 3D framework; COMPLEXES; CLUSTERS; MERCURY; IONS;
D O I：
10.1016/j.inoche.2010.11.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new mercury(II) complexes [Hg(TDMPT)Cl-2] (1) and [Hg-37(TDMPT)(12)Br-74] (2) (TDMPT = 2.4,6-tris(3,5-dimethylpyrazolyl)-1,3,5-triazine) have been prepared and characterized by X-ray structural analysis. Mercury(II) complex 1 is a mononuclear coordination compound. Meanwhile, mercury(II) complex 2 is the first example of the 3D coordination polymer wit h a 1D inorganic chain based on the Lindqvist-type [Hg6Br19](7-) anion as building blocks. Furthermore, the bromide anions act as terminal, mu(2)- and mu(6)-bridge ligands. (C) 2010 Elsevier B.V. All rights reserved.
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收藏
页码：243 / 246
页数：4
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