Superpositions of chiral states in the presence of electric dipole, magnetic dipole, and electric quadrupole interactions

被引:7
作者
Athalye, VS [1 ]
Kumar, A
机构
[1] Univ Bombay, Thakur Coll, Dept Phys, Bombay 400101, Maharashtra, India
[2] Tata Inst Fundamental Res, Homi Bhaba Ctr Sci Educ, Bombay 400088, Maharashtra, India
关键词
Degrees of freedom (mechanics) - Hamiltonians - Matrix algebra - Molecular dynamics - Perturbation techniques - Polarization - Radiation - Vacuum applications;
D O I
10.1063/1.1883645
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper is a straightforward generalization of Maierle-Harris proposal regarding parity implications on the superpositions of chiral states of a molecule. It is shown that the inclusion of electric quadrupole and magnetic dipole interactions removes several of restrictions on the preparation of superpositions of L and R states of a chiral molecule. It is also found that the dephasing of L and R superpositions, due to the spontaneous emission from the chiral molecule, has opposing contributions from electric quadrupole-magnetic dipole and electric dipole interactions. 2005 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 10 条
[1]   SUPERPOSITIONS OF HANDED WAVE-FUNCTIONS [J].
CINA, JA ;
HARRIS, RA .
SCIENCE, 1995, 267 (5199) :832-833
[2]   ON THE PREPARATION AND MEASUREMENT OF SUPERPOSITIONS OF CHIRAL AMPLITUDES [J].
CINA, JA ;
HARRIS, RA .
JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (04) :2531-2536
[3]   Analysis on the Cina-Harris proposal for the preparation and detection of chiral superposition states [J].
Duarte-Zamorano, RP ;
Romero-Rochín, V .
JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (21) :9276-9286
[4]   ON THE MEASUREMENT OF SUPERPOSITIONS OF CHIRAL AMPLITUDES BY POLARIZED-LIGHT SCATTERING [J].
HARRIS, RA ;
SHI, YM ;
CINA, JA .
JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (05) :3459-3463
[5]   ELECTRIC-FIELD OPTICAL-ACTIVITY, RAYLEIGH OPTICAL-ACTIVITY AND THE MEASUREMENT OF SUPERPOSITIONS OF CHIRAL AMPLITUDES [J].
HARRIS, RA ;
CINA, JA .
FARADAY DISCUSSIONS, 1994, 99 :369-373
[6]   Implications of parity conservation for superpositions of chiral states [J].
Maierle, CS ;
Harris, RA .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (10) :3713-3720
[7]  
MAIERLE CS, QUANTPH9807020
[8]   Radiative excitation of the harmonic oscillator with applications to stereomutation in chiral molecules [J].
Marquardt, R ;
Quack, M .
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1996, 36 (3-4) :229-237
[9]  
PFEIFFER P, 1983, P 2 WORKSH BIEL JUN, P315