Solubility of oxides in the BaCl2-KCl-NaCl (0.43:0.29:0.28) melt at 700°C

被引：0

作者：

Cherginets, VL ^{[1
]}

Rebrova, TP ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Single Crystals, UA-31041 Kharkov, Ukraine

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 46卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solubility products of MgO, NiO, CoO, MnO, ZnO, and CdO in the BaCl2-KCl-NaCl (0.43:0.29:0.28) melt at 700 degreesC were determined by potentiometric titration using a membrane oxygen electrode. The solubility of any oxide is about two orders of magnitude higher than that in rile KCl-NaCl (0.5:0.5) melt. The basicity index of BaCl2-KCl-NaCl melts was determined to be 2.01 +/- 0.3. The high acidity of Ba2+ compared to K+ and Na+ makes unpractical the use of barium-containing Lux-Flood bases in melts based on alkali metal halides (except for Lif).

引用

页码：295 / 297

页数：3

共 9 条

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