INTERACTION OF SINGLE-CRYSTALLINE METAL FLUORIDES WITH TITANIUM-CONTAINING MELTS

被引：4
|
作者：
Krasovskyy, V. P. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, Kiev, Ukraine
来源：
POWDER METALLURGY AND METAL CERAMICS | 2019年 / 58卷 / 5-6期
关键词：
contact interaction; liquid lithium and magnesium fluorides; solid titanium substrates; gaseous titanium fluorides; wetting; AMORPHOUS-ALLOYS; TI; CONTACT;
D O I：
10.1007/s11106-019-00083-y
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The wetting of solid titanium substrates with liquid lithium and magnesium fluorides was studied by the sessile drop method in 1.10(-3) Pa vacuum at 1173 and 1553 K, respectively. Titanium and fluorine were found to actively interact in the systems to change the titanium substrate surface profile, leading to a 'crater' in the contact area. The 'solid titanium-liquid magnesium fluoride' interfacial geometry was examined and confirmed the potential to form gaseous products in the titanium-fluorine interaction. Such gaseous compounds prevent the wetting of alkaline-earth metal fluorides with titanium-containing melts at temperatures above 1400 K. This allows the materials made of alkaline-earth metal fluorides to be used as refractories for high-temperature melting, long-term homogenization, and casting of alloys with a high content of Ti, Zr, Hf, Nb, and V.
引用
收藏
页码：334 / 340
页数：7
相关论文
共 50 条
  • [1] Interaction of Single-Crystalline Metal Fluorides with Titanium-Containing Melts
    V.P. Krasovskyy
    Powder Metallurgy and Metal Ceramics, 2019, 58 : 334 - 340
  • [2] ANODIC POLARIZATION IN CHLORIDE TITANIUM-CONTAINING MELTS.
    Voleinik, V.V.
    Olesov, Yu.G.
    Galochka, V.G.
    Lukoshnikov, I.E.
    Pavlov, V.V.
    Soviet progress in chemistry, 1984, 50 (04): : 76 - 78
  • [3] Thermodynamics of oxygen solutions in titanium-containing Fe–Co melts
    A. A. Aleksandrov
    V. Ya. Dashevskii
    L. I. Leont’ev
    Doklady Physical Chemistry, 2016, 471 : 173 - 177
  • [4] Solubility of oxygen in titanium-containing iron-nickel melts
    Aleksandrov A.A.
    Dashevskii V.Y.
    Steel in Translation, 2014, 44 (11) : 813 - 818
  • [5] Thermodynamics of the Oxygen Solutions in the Titanium-Containing Ni–Cr Melts
    Aleksandrov A.A.
    Dashevskii V.Y.
    Russian Metallurgy (Metally), 2018, 2018 (9) : 803 - 807
  • [6] Thermodynamics of oxygen solutions in titanium-containing Fe-Co melts
    Aleksandrov, A. A.
    Dashevskii, V. Ya.
    Leont'ev, L. I.
    DOKLADY PHYSICAL CHEMISTRY, 2016, 471 : 173 - 177
  • [7] Oxygen Solubility in Titanium-Containing Melts of the Ni-Co System
    Aleksandrov, A. A.
    Dashevskii, V. Ya.
    RUSSIAN METALLURGY, 2018, (11): : 1081 - 1087
  • [8] Thermodynamics of the Oxygen Solutions in Titanium-Containing Fe–Co–Cr Melts
    A. A. Aleksandrov
    V. Ya. Dashevskii
    Russian Metallurgy (Metally), 2019, 2019 : 531 - 535
  • [9] Elastic properties of single-crystalline ω phase in titanium
    Tane, M.
    Okuda, Y.
    Todaka, Y.
    Ogi, H.
    Nagakubo, A.
    ACTA MATERIALIA, 2013, 61 (20) : 7543 - 7554
  • [10] Thermodynamics of the Oxygen Solutions in Titanium-Containing Fe-Co-Cr Melts
    Aleksandrov, A. A.
    Dashevskii, V. Ya.
    RUSSIAN METALLURGY, 2019, 2019 (05): : 531 - 535
12345