Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties

被引：49
|
作者：
Centrone, Andrea [1 ]
Harada, Takuya [1 ]
Speakman, Scott [2 ]
Hatton, T. Alan [1 ]
机构：
[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
[2] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA
来源：
SMALL | 2010年 / 6卷 / 15期
基金：
美国国家科学基金会;
关键词：
magnetic properties; metal-organic frameworks; micro-wave synthesis; SQUID; XPS; HIGH-CAPACITY; SELECTIVE ADSORPTION; MICROWAVE SYNTHESIS; CARBON-DIOXIDE; STORAGE; HYDROGEN; METHANE; MIL-47; SEPARATION; CHEMISTRY;
D O I：
10.1002/smll.201000773
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The facile microwave syntheses of MIL-47 and six new vanadium-metal- organic-framework (V-MOF) materials are described. Small changes in the material crystal structure or removal of guest molecules affects the interactions between the V ions and, consequently, the magnetic properties of the MOF (see image). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA Weinheim.
引用
收藏
页码：1598 / 1602
页数：5
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