DART Mass Spectrometry in the Analysis of Organometallic Complexes

被引:0
作者
Goryainov, S. V. [1 ,2 ]
Esparza, C. [2 ]
Kulikova, L. N. [2 ]
Borisova, A. R. [2 ]
Kumandin, P. A. [2 ]
Antonova, A. S. [2 ]
Rystsova, E. O. [2 ]
Oshakbaev, M. T. [3 ]
Omarova, G. T. [3 ]
Polovkov, N. Yu. [1 ]
机构
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
[2] RUDN Univ, Moscow 117198, Russia
[3] Berkutov Inst Chem Sci, Alma Ata 050010, Kazakhstan
基金
俄罗斯科学基金会;
关键词
mass spectrometry; DART; organometallic complexes; Grubbs catalysts; ELECTROSPRAY-IONIZATION; REAL-TIME; ESI-MS; GRUBBS;
D O I
10.1134/S1061934821130049
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We recorded and interpreted DART mass spectra of Hoveyda-Grubbs catalysts with N -> Ru and S -> Ru coordination bonds. The set of ions formed under DART ionization conditions is similar to those obtained using matrix-assisted laser desorption/ionization mass spectrometry. The optimal conditions (ionization gas, gas flow temperature) for recording DART mass spectra of the studied compounds were determined.
引用
收藏
页码:1520 / 1524
页数:5
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