Etching-limited branching growth of cuprous oxide during ethanol-assisted solution synthesis

被引：40

作者：

Sun, Shaodong ^{[1
]}

You, Hongjun ^{[1
]}

Kong, Chuncai ^{[1
]}

Song, Xiaoping ^{[1
]}

Ding, Bingjun ^{[1
]}

Yang, Zhimao ^{[1
]}

机构：

[1] Xi An Jiao Tong Univ, Sch Sci, MOE Key Lab Nonequilibrium Synth & Modulat Conden, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 08期

基金：

国家高技术研究发展计划(863计划); 美国国家科学基金会;

关键词：

SHAPE-CONTROLLED SYNTHESIS; ONE-POT SYNTHESIS; METAL NANOSTRUCTURES; CU2O NANOCAGES; EVOLUTION; AGGREGATION; CRYSTALS; MICROCRYSTALS; TEMPERATURE; NANOFRAMES;

D O I：

10.1039/c1ce05151b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An etching-limited branching growth mechanism has been elucidated during ethanol-assisted solution synthesis of octahedral Cu2O crystals, which is different from the conventional diffusion-limited aggregate and recent overpotential-limited branching mechanism. It provides an innovative approach for revealing the shape evolution from habit formation (octahedron) to branching growth (hexapod-like architecture) via adjusting the competition between preferential growth and selective oxidative etching, and displays a constructive model system for fundamental research of crystal growth and design.

引用

收藏

页码：2837 / 2840

页数：4

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