Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]-

被引：5

作者：

Klyukin, I. N. ^{[1
]}

Kolbunova, A., V ^{[1
,2
]}

Selivanov, N. A. ^{[1
]}

Bykov, A. Yu ^{[1
]}

Zhdanov, A. P. ^{[1
]}

Zhizhin, K. Yu ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Natl Res Univ Higher Sch Econ, Moscow 101000, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

boron cluster anions; closo-decaborates; carbonyl derivatives; CLUSTER; DECAHYDRODECABORATE; ASTATINATION; REAGENTS; BONDS; N=6;

D O I：

10.1134/S003602362112007X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Currently, the chemistry of carbonyl derivatives of the closo-borate anions is actively developing. It is of great interest to obtain protonated complexes of these types of clusters for further directed functionalization. The aim of this study is to develop an approach to the preparation of the protonated complex of the monocarbonyl derivative [B10H9CO.H-fac](0). In the course of the work, the target complex has been obtained by protonation of the [B10H9CO](-) anion with an excess of trifluoromethanesulfonic acid CF3SO3OH. In this reaction, the boron cluster is quantitatively protonated. When a base is added, the protonation process becomes reversible.

引用

页码：1798 / 1801

页数：4

共 21 条

[1] New triethoxysilylated 10-vertex closo-decaborate clusters. Synthesis and controlled immobilization into mesoporous silica [J].

Abi-Ghaida, Fatima ;

Laila, Zahra ;

Ibrahim, Ghassan ;

Naoufal, Daoud ;

Mehdi, Ahmad .

DALTON TRANSACTIONS, 2014, 43 (34) :13087-13095

[2] Boron Chemistry for Medical Applications [J].

Ali, Fayaz ;

Hosmane, Narayan S. ;

Zhu, Yinghuai .

MOLECULES, 2020, 25 (04)

[3] Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review) [J].

Avdeeva, V. V. ;

Malinina, E. A. ;

Zhizhin, K. Yu. ;

Kuznetsov, N. T. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (04) :514-534

[4] Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate [J].

Diab, Manal ;

Mateo, Ana ;

Al Cheikh, Joumada ;

Haouas, Mohamed ;

Ranjbari, Alireza ;

Bourdreux, Flavien ;

Naoufal, Daoud ;

Cadot, Emmanuel ;

Bo, Carles ;

Floquet, Sebastien .

DALTON TRANSACTIONS, 2020, 49 (15) :4685-4689

[5] Synthesis of New Bioinorganic Systems Based on Nitrilium Derivatives of closo-Decaborate Anion and meso-Arylporphyrins with Pendant Amino Groups [J].

Ezhov, Artem V. ;

Vyal'ba, Fedor Yu. ;

Kluykin, Ilya N. ;

Zhdanova, Kseniya A. ;

Bragina, Natal'ya A. ;

Zhdanov, Andrey P. ;

Zhizhin, Konstantin Yu. ;

Mironov, Andrey F. ;

Kuznetsov, Nikolay T. .

MACROHETEROCYCLES, 2017, 10 (04) :505-509

[6] ELECTROPHILIC REACTIONS OF PROTONATED CLOSO-B10H10(2-) WITH ARENES, ALKANE C-H BONDS, AND TRIFLATE ION FORMING ARYL, ALKYL, AND TRIFLATE NIDO-6-X-B10H13 DERIVATIVES [J].

HAWTHORNE, MF ;

MAVUNKAL, IJ ;

KNOBLER, CB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4427-4429

[7] [closo-B10H10]2- as a structural element for quadrupolar liquid crystals: a new class of liquid crystalline NLO chromophores [J].

Jankowiak, Aleksandra ;

Balinski, Andrzej ;

Harvey, James E. ;

Mason, Kristein ;

Januszko, Adam ;

Kaszynski, Piotr ;

Young, Victor G., Jr. ;

Persoons, Andre .

JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (06) :1144-1159

[8] HALOGENATION OF 4,5-DICARBA-ARACHNO-NONABORANE(13),4,5-C2B7H13 [J].

JELINEK, T ;

STIBR, B ;

MARES, F ;

PLESEK, J ;

HERMANEK, S .

POLYHEDRON, 1987, 6 (09) :1737-1740

[9] The new approach to formation of exo boron-oxygen bonds from the decahydro-closo-decaborate(2-) anion [J].

Klyukin, I. N. ;

Kubasov, A. S. ;

Limarev, I. P. ;

Zhdanov, A. P. ;

Matveev, E. Yu. ;

Polyakova, I. N. ;

Zhizhin, K. Yu. ;

Kuznetsov, N. T. .

POLYHEDRON, 2015, 101 :215-222

[10] Theoretical study of closo-borate derivatives of general type [BnHn-1COR]2- (n=6, 10, 12; R = H, CH3, NH2, OH, OCH3) - Borylated analogue of organic carbonyl compounds [J].

Klyukin, Ilya N. ;

Novikov, Alexander S. ;

Zhdanov, Andrey P. ;

Zhizhin, Konstantin Yu ;

Kuznetsov, Nikolay T. .

POLYHEDRON, 2020, 187

← 1 2 3 →