Nanofluidics in carbon nanotubes

被引:309
作者
Noy, Ateksandr [1 ]
Park, Hyung Gyu [1 ,2 ]
Fornasiero, Francesco [1 ]
Holt, Jason K. [1 ]
Grigoropoulos, Costas P. [2 ]
Bakajin, Olgica [1 ]
机构
[1] Lawrence Livermore Natl Lab, Mat & Life Sci Directorate, Mol Biophys & Funct Nanostruct Grp, Livermore, CA 94550 USA
[2] Univ Calif Berkeley, Dept Mech Engn, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/S1748-0132(07)70170-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Extremely high aspect ratios, molecularly smooth hydrophobic graphitic walls, and nanoscale inner diameters of carbon nanotubes give rise to the unique phenomenon of ultra-efficient transport of water and gas through these ultra-narrow molecular pipes. Water and gas molecules move through nanotube pores orders of magnitude faster than through other pores of comparable size. The proposed water transport mechanism has a distinct similarity to the transport mechanisms of biological ion channels. Molecular dynamics simulations and experimental measurements of water transport underscore the importance of nanotube structure in enabling ultra-efficient transport through the pore.
引用
收藏
页码:22 / 29
页数:8
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