A novel cobalt-carbon composite for the electrochemical supercapacitor electrode material

被引:31
|
作者
Wei, Fuxiang [1 ]
Jiang, Jiaqiang [1 ]
Yu, Genxi [1 ]
Sui, Yanwei [1 ]
机构
[1] China Univ Min & Technol, Sch Mat Sci & Engn, Xuzhou 221008, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal-organic framework; Cobalt/carbon composites; X-ray techniques; Nanoparticles; Supercapacitor; ZEOLITIC IMIDAZOLATE FRAMEWORK; HYDROGEN STORAGE CAPACITY; METAL-ORGANIC FRAMEWORK; ACTIVATED CARBON; PERFORMANCE; NANORODS;
D O I
10.1016/j.matlet.2015.01.143
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Metallic cobalt/carbon composites were synthesized by metal-organic framework as precursor via a facile method in the paper. The obtained cobalt nanoparticles are 5-10 nm in size and anchor on carbon homogeneously. The results indicate that metallic cobalt particles have excellent dispersion feature on the surface of carbon. The electrochemical performance of metallic cobalt/carbon composites was characterized by Cyclic voitammetry (CV) and galvanostatic charge/discharge tests. The specific capacitance of the composite material is up to 144.5 F g(-1) at current density of 0.5 A g(-1) with a capacitance retention rate of 96.5% at current density of 2 A g(-1). The results suggest that synergistic performance can be achieved by combining metallic cobalt and carbon, which inherits the overall system with enhanced electrochemical performance. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:20 / 22
页数:3
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