Syntheses and Structural Characterization of 1D Chain and 1D Ladder Coordination Polymers Assembled from Exo-bidentate Imidazolyl Ligands

被引：6

作者：

Jin, Shouwen ^{[1
]}

Wang, Daqi ^{[2
]}

Zheng, Zhiwen ^{[1
]}

Chen, Jie ^{[1
]}

Feng, Chao ^{[1
]}

Ye, Xianghua ^{[1
]}

Zhou, Yiping ^{[1
]}

机构：

[1] ZheJiang Forestry Univ, Fac Sci, Linan 311300, Peoples R China

[2] Liaocheng Univ Liaocheng, Dept Chem, Liaocheng 252059, Shandong, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 08期

关键词：

Coordination polymers; Zinc; Copper; Cadmium; Imidazolyl ligands; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURE; COMPLEXES; ADSORPTION; NETWORKS; SORPTION; BEHAVIOR; CO(II); 1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE; NI-2(4,4'-BIPYRIDINE)(3)(NO3)(4);

D O I：

10.1002/zaac.200900556

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five novel coordination polymers, [(Cu(L-1)(2)OH)center dot Cl.3H(2)O] (1) [L-1 = bis(N-imidazolyl)methane], [Cd(L-1)(2)(NCS)(2)] (2), [Zn(L-1)(2)(NCS)(2)] (3), [Cu(L-1)(2)(NO3)(2)] (4), and [Cu(L-2)(1.5)(NCS)(2)] (5) [L-2= I,4-bis(N-imidazolyl)butane] were obtained from self-assembly of the corresponding metal salts with flexible ligands and their structures were fully characterized by X-ray diffraction (XRD) analysis, Fourier Transform Infrared (FT-IR) spectroscopy, elemental analysis and thermogravimetric (TGA) measurements. X-ray diffraction analyses revealed that complexes I, 2, 3, and 4 exhibit ID double-stranded chain structures, which result from doubly bridged [CuOH], [M(NCS)(2)] (M= Cd, Zn), and [Cu(NO3)(2)] units, respectively. The polymeric copper complex 5 displays ID ladder structure., These complexes, with the exception of complex 1, are stable up to 300 degrees C.

引用

页码：1617 / 1624

页数：8

共 54 条

[1] Anion-dependence of the polymeric structures of manganese(II) complexes of N,N′-butylenebis(imidazole) [J].

Ballester, L ;

Baxter, I ;

Duncan, PCM ;

Goodgame, DML ;

Grachvogel, DA ;

Williams, DJ .

POLYHEDRON, 1998, 17 (20) :3613-3623

[2] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[3] Preparation, crystal structures and magnetic properties of three thiocyanato-bridged copper(II) complexes with 2,2′-biimidazole or 2-(2′-pyridyl)imidazole as terminal ligands [J].

Carranza, Jose ;

Sletten, Jorunn ;

Lloret, Francesc ;

Julve, Miguel .

POLYHEDRON, 2009, 28 (11) :2249-2257

[4] Reactions of [Cd(SCN)2] and isonicotinonitrile, synthesis and X-ray characterization of 1-and 3D coordination polymers, [Cd(SCN)2-(pyCNn)] (pyCN=isonicotinonitrile, n=1,2) [J].

Chen, WZ ;

Liu, FH ;

You, XZ .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (07) :1559-1560

[5] Multidimensional metal-organic frameworks constructed from flexible bis(imidazole) ligands [J].

Cui, GH ;

Li, JR ;

Tian, JL ;

Bu, XH ;

Batten, SR .

CRYSTAL GROWTH & DESIGN, 2005, 5 (05) :1775-1780

[6] Flexible sorption and transformation behavior in a microporous metal-organic framework [J].

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ ;

Kepert, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) :9574-9581

[7] New crystalline frameworks formed from 1,2-bis(4-pyridyl)ethyne and Co(NO3)2:: Interpenetrating molecular ladders and an unexpected molecular parquet pattern from T-shaped building blocks [J].

Dong, YB ;

Layland, RC ;

Pschirer, NG ;

Smith, MD ;

Bunz, UHF ;

zur Loye, HC .

CHEMISTRY OF MATERIALS, 1999, 11 (06) :1413-+

[8] Formation of an infinite interpenetrating three-dimensional network by tris(N,N'-butylenebisimidazole)manganese(II) tetrafluoroborate [J].

Duncan, PCM ;

Goodgame, DML ;

Menzer, S ;

Williams, DJ .

CHEMICAL COMMUNICATIONS, 1996, (18) :2127-2128

[9] Adsorption of gases and vapors on nanoporous Ni2(4,4′-bipyridine)3(NO3)4 metal-organic framework materials templated with methanol and ethanol:: Structural effects in adsorption kinetics [J].

Fletcher, AJ ;

Cussen, EJ ;

Bradshaw, D ;

Rosseinsky, MJ ;

Thomas, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) :9750-9759

[10] Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni2(4,4′-bipyridine)3(NO3)4:: Guest modification of host sorption behavior [J].

Fletcher, AJ ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ ;

Kepert, CJ ;

Thomas, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :10001-10011

← 1 2 3 4 5 6 →