A molecularly imprinted polymers/carbon dots-grafted paper sensor for 3-monochloropropane-1,2-diol determination

被引:72
作者
Fang, Min [1 ,2 ]
Zhou, Lv [1 ,2 ]
Zhang, Hu [1 ,2 ]
Liu, Liang [1 ,2 ]
Gong, Zhi-Yong [1 ,2 ]
机构
[1] Wuhan Polytech Univ, Inst Food Sci & Engn, Wuhan 430023, Hubei, Peoples R China
[2] Wuhan Polytech Univ, Hubei Collaborat Innovat Ctr Proc Agr Prod, Wuhan, Hubei, Peoples R China
关键词
Paper-based sensor; Molecularly imprinted polymers (MIPs); Carbon dot; 3-Chloro-1,2-propandiol; Fluorescence; FLUORESCENCE DETECTION; MICROFLUIDIC CHIP; QUANTUM DOTS; CARBON DOTS; EXTRACTION; POLYMER; 3-MCPD; WATER; 3-CHLORO-1,2-PROPANEDIOL; PERSPECTIVES;
D O I
10.1016/j.foodchem.2018.08.133
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
3-Monochloropropane-1,2-diol (3-MCPD) is a common food processing contaminant and a simple, rapid, sensitive and low cost monitoring technology is needed due to its potential carcinogenic nature. Carbon dots directly intercepted on filter paper provide high fluorescence intensity and can be adapted for use as a sensor. We synthesized a carbon dot-filter paper in combination with a molecularly imprinted polymeric film to extract 3-MCPD from samples. This grafted paper-based sensor exhibited a high adsorption capacity (68.97 mg g(-1)), an excellent selectivity (imprinting factor = 4.5) and a low detection limit (0.6 ng mL(-1)). Recoveries ranged from 97.2% to 105.3% with relative standard deviations < 5.6%. The results obtained using this method were linearly correlated to those of the classic GC-MS method (r = 0.998). Based on the Chinese National Standard, this study provides a novel and powerful platform for the simple, rapid, sensitive and on-site analysis of 3-MCPD in soy sauce.
引用
收藏
页码:156 / 161
页数:6
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