Enhanced electrochemical supercapacitor properties with synergistic effect of polyaniline, graphene and AgxO

被引:27
作者
Usman, Muhammad [1 ]
Pan, Lujun [1 ]
Asif, Muhammad [1 ,2 ]
Mahmood, Zafar [3 ]
Khan, M. A. [4 ]
Fu, Xin [1 ]
机构
[1] Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
[3] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[4] BUITEMS, Dept Phys, Quetta 87300, Pakistan
基金
中国国家自然科学基金;
关键词
Graphene; Polyaniline; AgxO; Supercapacitor; HIGH-PERFORMANCE; ACTIVATED CARBON; HYDROTHERMAL SYNTHESIS; ELECTRODE MATERIALS; OXYGEN REDUCTION; FACILE SYNTHESIS; THIN-FILMS; OXIDE; SILVER; NANOCOMPOSITES;
D O I
10.1016/j.apsusc.2016.02.175
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The graphene-Ag2O/polyaniline (GAP) composite has been synthesized by in-situ polymerization. It has been observed that Ag2O nanoparticles exist on the porous spongy background of PANI (polyaniline). The optimized composition of the synthesized composite exhibits an extraordinary specific capacitance of 1572 Fg(-1) at 0.05 Ag-1 current density and good cyclic stability of 85% over 3000 charge-discharge cycles. The extraordinary electrochemical performance indicates the positive synergistic effect of PANI, graphene and Ag2O. The Ag2O nanoparticles might be responsible for improved electrical conductivity, and graphene might contribute in enhancing the electrochemical stability of the PANI electrode. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:297 / 305
页数:9
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