Kinetics and mechanism of oxidation of cyclohexanone by quinolinium dichromate

被引:0
作者
Das, S [1 ]
Mahanti, MK [1 ]
机构
[1] NE Hill Univ, Dept Chem, Shillong 793003, Meghalaya, India
来源
OXIDATION COMMUNICATIONS | 2000年 / 23卷 / 04期
关键词
mechanism; oxidation; cyclohexanone; quinolinium dichromate; sulphuric acid;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cyclohexanone is oxidised to adipic acid by quinolinium dichromate in aqueous acetic acid medium, in the presence of sulphuric acid. The reaction proceeded via the formation of enol. The slow step involved the reaction of the enol with the oxidant.
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页码:495 / 499
页数:5
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