2D hybrid anode based on SnS nanosheet bonded with graphene to enhance electrochemical performance for lithium-ion batteries

被引:79
作者
Li, Shuankui [1 ,2 ]
Zheng, Jiaxin [2 ]
Zuo, Shiyong [1 ]
Wu, Zhiguo [1 ]
Yan, Pengxun [1 ]
Pan, Feng [2 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China
[2] Peking Univ, Shenzhen Grad Sch, Sch Adv Mat, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
STORAGE; NANORODS; CAPACITY; OXIDE;
D O I
10.1039/c5ra07292a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hybrid anode based on SnS nanosheets bonded with reduced graphene oxide (SnS NS/RGO) and synthesized with graphene oxide is formed through a facile solvothermal method. It is found that the 2D SnS nanosheets with few layers are well dispersed on the crumpled reduced graphene oxide surface. Electrochemical tests indicate that the SnS NS/RGO hybrid exhibits a very high reversible capacity (791 mA h g(-1)) with excellent cycle stability and significantly enhanced rate capability. The factors contributing to the enhanced electrochemical performance of the hybrid anode can be ascribed to the chemically bonded interface between SnS NS and RGO, creating effective charge transportation with electron coupling in the novel two-dimensional composite nanostructure. This work provides insights into the structural design of SnS-based hybrid electrode materials, which will be important for the future development of high performance electrode materials.
引用
收藏
页码:46941 / 46946
页数:6
相关论文
共 29 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]   Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage [J].
Bonaccorso, Francesco ;
Colombo, Luigi ;
Yu, Guihua ;
Stoller, Meryl ;
Tozzini, Valentina ;
Ferrari, Andrea C. ;
Ruoff, Rodney S. ;
Pellegrini, Vittorio .
SCIENCE, 2015, 347 (6217)
[4]   A comparative study of lithium-storage performances of hematite: Nanotubes vs. nanorods [J].
Chen, Liang ;
Xu, Huayun ;
Li, Li'e ;
Wu, Fangfang ;
Yang, Jian ;
Qian, Yitai .
JOURNAL OF POWER SOURCES, 2014, 245 :429-435
[5]   Aligned Carbon Nanotube-Silicon Sheets: A Novel Nano-architecture for Flexible Lithium Ion Battery Electrodes [J].
Fu, Kun ;
Yildiz, Ozkan ;
Bhanushali, Hardik ;
Wang, Yongxin ;
Stano, Kelly ;
Xue, Leigang ;
Zhang, Xiangwu ;
Bradford, Philip D. .
ADVANCED MATERIALS, 2013, 25 (36) :5109-5114
[6]  
Han X. Y., 2012, ANGEW CHEM INT EDIT, V51, P1
[7]   25th Anniversary Article: Hybrid Nanostructures Based on Two-Dimensional Nanomaterials [J].
Huang, Xiao ;
Tan, Chaoliang ;
Yin, Zongyou ;
Zhang, Hua .
ADVANCED MATERIALS, 2014, 26 (14) :2185-2204
[8]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[9]   Localized surface plasmon resonance in SnS:Ag nano-composite films [J].
Jain, Priyal ;
Arun, P. .
JOURNAL OF APPLIED PHYSICS, 2014, 115 (20)
[10]  
Kamaya N, 2011, NAT MATER, V10, P682, DOI [10.1038/NMAT3066, 10.1038/nmat3066]