Synthesis and spectroscopic properties of β-meso directly linked porphyrin-corrole hybrid compounds

被引：7

作者：

Temelli, Baris ^{[1
]}

Kalkan, Hilal ^{[1
]}

机构：

[1] Hacettepe Univ, Dept Chem, Beytepe Campus, TR-06800 Ankara, Turkey

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 14卷

关键词：

corrole; hybrid compounds; indium(III) chloride; porphyrin; porphyrinoids; PHOTOINDUCED CHARGE SEPARATION; MESOSUBSTITUTED CORROLES; ELECTRON-TRANSFER; DYADS; CONJUGATE; SPECTROELECTROCHEMISTRY; ELECTROCHEMISTRY; BINDING; SYSTEM; TRIAD;

D O I：

10.3762/bjoc.14.13

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of beta-meso directly linked porphyrin-corrole hybrids was realized for the first time via an InCl3-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with meso-substituted dipyrromethanes. Hybrid compounds have been characterized by H-1 NMR, C-13 NMR, 2D NMR, UV-vis absorption and fluorescence spectroscopy.

引用

页码：187 / 193

页数：7

共 42 条

[1]

Aratani N., 2010, HDB PORPHYRIN SCI, V1, P1

[2] Corrole-based applications [J].

Aviv, Iris ;

Gross, Zeev .

CHEMICAL COMMUNICATIONS, 2007, (20) :1987-1999

[3] Strategies for Corrole Functionalization [J].

Barata, Joana F. B. ;

Neves, M. Graca P. M. S. ;

Faustino, M. Amparo F. ;

Tome, Augusto C. ;

Cavaleiro, Jose A. S. .

CHEMICAL REVIEWS, 2017, 117 (04) :3192-3253

[4] Supramolecular Chemistry of Metalloporphyrins [J].

Beletskaya, Irina ;

Tyurin, Vladimir S. ;

Tsivadze, Aslan Yu. ;

Guilard, Roger ;

Stern, Christine .

CHEMICAL REVIEWS, 2009, 109 (05) :1659-1713

[5] Syntheses, Crystal Structure, and Spectroscopic Properties of Meso-Meso-Linked Porphyrin-Corrole Hybrids [J].

Chen, Chen ;

Zhu, Yi-Zhou ;

Fan, Qiao-Jun ;

Song, Hai-Bin ;

Zheng, Jian-Yu .

CHEMISTRY LETTERS, 2013, 42 (08) :936-938

[6] A π-Stacked Porphyrin-Fullerene Electron Donor-Acceptor Conjugate That Features a Surprising Frozen Geometry [J].

Ciammaichella, Alina ;

Dral, Pavlo O. ;

Clark, Timothy ;

Tagliatesta, Pietro ;

Sekita, Michael ;

Guldi, Dirk M. .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (44) :14008-14016

[7]

Dolphin D., 1979, The Porphyrins

[8] A FULLERENE PORPHYRIN CONJUGATE [J].

DROVETSKAYA, T ;

REED, CA ;

BOYD, P .

TETRAHEDRON LETTERS, 1995, 36 (44) :7971-7974

[9] Photophysical properties of a new, stable corrole-porphyrin dyad [J].

Flamigni, Lucia ;

Ventura, Barbara ;

Tasior, Mariusz ;

Gryko, Daniel T. .

INORGANICA CHIMICA ACTA, 2007, 360 (03) :803-813

[10] Synthesis and Stereochemistry of Highly Unsymmetric β,Meso-Linked Porphyrin Arrays [J].

Gotz, Daniel C. G. ;

Bruhn, Torsten ;

Senge, Mathias O. ;

Bringmann, Gerhard .

JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (21) :8005-8020

← 1 2 3 4 5 →