Tuning the Photoresponse in Organic Field-Effect Transistors

被引:91
作者
El Gemayel, Mirella [1 ]
Treier, Matthias [1 ]
Musumeci, Chiara [1 ]
Li, Chen [2 ]
Muellen, Klaus [2 ]
Samori, Paolo [1 ]
机构
[1] Univ Strasbourg, ISIS CNRS 7006, Nanochem Lab, F-67000 Strasbourg, France
[2] Max Planck Inst Polymer Res, D-55124 Mainz, Germany
关键词
PERYLENE BISIMIDE DYES; THIN-FILM TRANSISTORS; SELF-ORGANIZATION; SOLAR-CELLS; SEMICONDUCTORS; PERFORMANCE; PHOTOTRANSISTORS; ARCHITECTURE; NANOSCALE; DIIMIDES;
D O I
10.1021/ja211515b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on the fabrication of solution-processed organic phototransistors (OPTs) based on perylenebis(dicarboximide)s (PDIs). We found that the responsivity to the photoillumination depends on the transistor's channel length and that it can be tuned by varying the device geometry. The analysis of different morphologies of the active semiconducting layer revealed. that single PDI fibers exhibit the higher photoresponse when compared to more poorly organized films. The highest responsivity value of 4.08 +/- 1.65 x 10(5) A/W was achieved on a multifiber-based OPT. These findings represent a step forward toward the use of organic based phototransistors as photosensors.
引用
收藏
页码:2429 / 2433
页数:5
相关论文
共 36 条
  • [1] n-Type Organic Semiconductors in Organic Electronics
    Anthony, John E.
    Facchetti, Antonio
    Heeney, Martin
    Marder, Seth R.
    Zhan, Xiaowei
    [J]. ADVANCED MATERIALS, 2010, 22 (34) : 3876 - 3892
  • [2] Photoinduced long-term memory effects in n-type organic perylene transistors
    Barra, M.
    Bloisi, F.
    Cassinese, A.
    Di Girolamo, F. V.
    Vicari, L.
    [J]. JOURNAL OF APPLIED PHYSICS, 2009, 106 (12)
  • [3] Perylenediimide nanowires and their use in fabricating field-effect transistors and complementary inverters
    Briseno, Alejandro L.
    Mannsfeld, Stefan C. B.
    Reese, Colin
    Hancock, Jessica M.
    Xiong, Yujie
    Jenekhe, Samson A.
    Bao, Zhenan
    Xia, Younan
    [J]. NANO LETTERS, 2007, 7 (09) : 2847 - 2853
  • [4] Improved air stability of n-channel organic thin-film transistors with surface modification on gate dielectrics
    Chen, Fang-Chung
    Liao, Cheng-Hsiang
    [J]. APPLIED PHYSICS LETTERS, 2008, 93 (10)
  • [5] Organic thin film transistors based on N-alkyl perylene diimides:: Charge transport kinetics as a function of gate voltage and temperature
    Chesterfield, RJ
    McKeen, JC
    Newman, CR
    Ewbank, PC
    da Silva, DA
    Brédas, JL
    Miller, LL
    Mann, KR
    Frisbie, CD
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50) : 19281 - 19292
  • [6] Probing conformational dynamics in single donor-acceptor synthetic molecules by means of photoinduced reversible electron transfer
    Cotlet, M
    Masuo, S
    Luo, GB
    Hofkens, J
    Van der Auweraer, M
    Verhoeven, J
    Müllen, K
    Xie, XLS
    De Schryver, F
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (40) : 14343 - 14348
  • [7] Energy dissipation in multichromophoric single dendrimers
    De Schryver, FC
    Vosch, T
    Cotlet, M
    Van der Auweraer, M
    Müllen, K
    Hofkens, J
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (07) : 514 - 522
  • [8] Tuning the Charge-Transport Parameters of Perylene Diimide Single Crystals via End and/or Core Functionalization: A Density Functional Theory Investigation
    Delgado, M. Carmen Ruiz
    Kim, Eung-Gun
    da Silva Filho, Demetrio A.
    Bredas, Jean-Luc
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (10) : 3375 - 3387
  • [9] Crystal network formation in organic solar cells
    Dittmer, JJ
    Lazzaroni, R
    Leclère, P
    Moretti, P
    Granström, M
    Petritsch, K
    Marseglia, EA
    Friend, RH
    Brédas, JL
    Rost, H
    Holmes, AB
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 61 (01) : 53 - 61
  • [10] Molecular materials by self-assembly of porphyrins, phthalocyanines, and perylenes
    Elemans, Johannes A. A. W.
    Van Hameren, Richard
    Nolte, Roeland J. M.
    Rowan, Alan E.
    [J]. ADVANCED MATERIALS, 2006, 18 (10) : 1251 - 1266