Synthesis and characterizations of Cu2MgSnS4 thin films with different sulfuration temperatures

被引：27

作者：

Yang, Gang ^{[1
,2
]}

Zhai, Xiaoli ^{[1
]}

Li, Yongfeng ^{[1
,3
,4
]}

Yao, Bin ^{[1
,3
,4
]}

Ding, Zhanhui ^{[1
,3
,4
]}

Deng, Rui ^{[5
]}

Zhao, Haifeng ^{[6
]}

Zhang, Ligong ^{[6
]}

Zhang, Zhenzhong ^{[6
]}

机构：

[1] Jilin Univ, Coll Phys, Minist Educ, Key Lab Phys & Technol Adv Batteries, Changchun 130012, Jilin, Peoples R China

[2] Nanyang Normal Univ, Coll Phys & Elect Engn, Nanyang 473061, Peoples R China

[3] Jilin Univ, State Key Lab Superhard Mat, Changchun 130023, Jilin, Peoples R China

[4] Jilin Univ, Coll Phys, Changchun 130023, Jilin, Peoples R China

[5] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Jilin, Peoples R China

[6] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Luminescence & Applicat, 3888 Dongnanhu Rd, Changchun 130033, Jilin, Peoples R China

来源：

MATERIALS LETTERS | 2019年 / 242卷

基金：

中国国家自然科学基金;

关键词：

Cu2MgSnS4; Thin films; Zinc-blende; Optical properties; Electrical properties; CU2MNSNS4;

D O I：

10.1016/j.matlet.2019.01.102

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cu2MgSnS4 thin films were prepared by sol-gel spin-coating route followed by sulfuration. The effects of the annealing temperature on structural, optical and electrical characteristics were investigated. All the annealed CMTS thin films show Cu-poor and slightly S-poor condition. X-ray diffraction and X-ray photoelectron spectroscopy results reveal the formation of zinc-blende structure CMTS thin films. The increase of sulfurization temperature improves the crystallinity and diminishes the bandgaps of CMTS films. The CMTS solar cell shows a better efficiency of 0.78% with the optimized temperature of 530 degrees C. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：58 / 61

页数：4

共 16 条

[1]

[Anonymous], 2011, Phys. Rev. B

[2] Efficiency enhancement by adding SnS powder during selenization for Cu2ZnSn(S,Se)4 thin film solar cells [J].

Cai, Chung-Hao ;

Wei, Shih-Yuan ;

Huang, Wei-Chih ;

Lin, Jeff ;

Yeh, Tzu-Hsuan ;

Lai, Chih-Huang .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2016, 145 :296-302

[3] Influence of annealing temperature on structural and optical properties of Cu2MnSnS4 thin films fabricated by sol-gel [J].

Chen, Leilei ;

Deng, Hongmei ;

Tao, Jiahua ;

Zhou, Wenliang ;

Sun, Lin ;

Yue, Fangyu ;

Yang, Pingxiong ;

Chu, Junhao .

JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 640 :23-28

[4] The structural, morphological and optical-electrical characteristic of Cu2XSnS4 (X:Cu,Mg) thin films fabricated by novel ultrasonic co-spray pyrolysis [J].

Guo, Yixin ;

Cheng, Wenjuan ;

Jiang, Jinchun ;

Zuo, Shaohua ;

Shi, Fuwen ;

Chu, Junhao .

MATERIALS LETTERS, 2016, 172 :68-71

[5] Substitution of Zn in Earth-Abundant Cu2ZnSn(S,Se)4 based thin film solar cells A status review [J].

Kumar, M. Suresh ;

Madhusudanan, Sreejith P. ;

Batabyal, Sudip K. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2018, 185 :287-299

[6] Dilute magnetic semiconductor Cu2MnSnS4 nanocrystals with a novel zincblende and wurtzite structure [J].

Liang, Xiaolu ;

Guo, Peng ;

Wang, Gang ;

Deng, Ruiping ;

Pan, Daocheng ;

Wei, Xianhua .

RSC ADVANCES, 2012, 2 (12) :5044-5046

[7] Alloyed (ZnS)x(Cu2SnS3)1-x and (CuInS2)x(Cu2SnS3)1-x nanocrystals with arbitrary composition and broad tunable band gaps [J].

Liu, Qinghui ;

Zhao, Zechen ;

Lin, Yuhan ;

Guo, Peng ;

Li, Shenjie ;

Pan, Daocheng ;

Ji, Xiangling .

CHEMICAL COMMUNICATIONS, 2011, 47 (03) :964-966

[8] The path towards a high-performance solution-processed kesterite solar cell [J].

Mitzi, David B. ;

Gunawan, Old ;

Todorov, Teodor K. ;

Wang, Kejia ;

Guha, Supratik .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (06) :1421-1436

[9] Photovoltaic effect in earth abundant solution processed Cu2MnSnS4 and Cu2MnSn(S,Se)4 thin films [J].

Prabhakar, Rajiv Ramanujam ;

Su Zhenghua ;

Xin, Zeng ;

Baikie, Tom ;

Woei, Leow Shin ;

Shukla, Sudhanshu ;

Batabyal, Sudip K. ;

Gunawan, Oki ;

Wong, Lydia Helena .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2016, 157 :867-873

[10] The Consequences of Kesterite Equilibria for Efficient Solar Cells [J].

Redinger, Alex ;

Berg, Dominik M. ;

Dale, Philip J. ;

Siebentritt, Susanne .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (10) :3320-3323

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