New, effective method of synthesis and structural characterization of octakis(3-chloropropyl)octasilsesquioxane

被引：75
作者：
Marciniec, Bogdan [1 ]
Dutkiewicz, Michal [1 ]
Maciejewski, Hieronim [1 ]
Kubicki, Maciej [1 ]
机构：
[1] Adam Mickiewicz Univ, Dept Organomet Chem, Fac Chem, PL-60780 Poznan, Poland
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 04期
关键词：
18;
D O I：
10.1021/om700962x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Our new synthesis of octakis(3-chloropropyl)octasilsesquioxane (1) is based on a two-stage hydrolytic condensation of 3-chloropropyltrimethoxysilane. This enables the selective formation of the desired product more rapidly (4 days), in comparison to methods used to date (5 weeks), while the yield (35%) is comparable. The process is,conducted in methanolic solution, with the first stage being acid hydrolysis and the second stage condensation in the presence of di-n-butyltin dilaurate as a catalyst.
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页码：793 / 794
页数：2
相关论文
共 17 条
  • [1] SILSESQUIOXANES
    BANEY, RH
    ITOH, M
    SAKAKIBARA, A
    SUZUKI, T
    [J]. CHEMICAL REVIEWS, 1995, 95 (05) : 1409 - 1430
  • [2] BIERLIN AA, 1960, USPH KHIM, V29, P1189
  • [3] Brook, 2000, SILICON ORGANIC ORGA, P282
  • [4] Polysilsesquioxanes and oligosilsesquioxanes substituted by alkylammonium salts as antibacterial biocides
    Chojnowski, J.
    Fortuniak, W.
    Rosciszewski, P.
    Werel, W.
    Lukasiak, J.
    Kamysz, W.
    Halasa, R.
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2006, 16 (03) : 219 - 230
  • [5] FUNCTIONALIZED OCTA-(PROPYLSILSESQUIOXANES) (3-XC(3)H(6))(8)(SI8O12) - MODEL COMPOUNDS FOR SURFACE-MODIFIED SILICA-GELS
    DITTMAR, U
    HENDAN, BJ
    FLORKE, U
    MARSMANN, HC
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) : 185 - 194
  • [6] SILASESQUIOXANES AS LIGANDS IN INORGANIC AND ORGANOMETALLIC CHEMISTRY
    FEHER, FJ
    BUDZICHOWSKI, TA
    [J]. POLYHEDRON, 1995, 14 (22) : 3239 - 3253
  • [7] SILANE-SILANOL CONDENSATION CATALYZED BY ORGANOTIN COMPOUNDS
    FIERENS, P
    VANDENDUNGHEN, G
    SEGERS, W
    VANELSUWE, R
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 1978, 8 (02): : 179 - 187
  • [8] Kickelbick G, 2007, HYBRID MAT SYNTHESIS, DOI DOI 10.1002/9783527610495.CH2
  • [9] Star-shaped poly(ε-caprolactone) with polyhedral oligomeric silsesquioxane core
    Liu, Yonghong
    Yang, Xingtian
    Zhang, Weian
    Zheng, Sixun
    [J]. POLYMER, 2006, 47 (19) : 6814 - 6825
  • [10] Synthesis and structures of gamma-halopropyl-octa(silasesquioxanes)
    Lucke, S
    StoppekLangner, K
    Krebs, B
    Lage, M
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (08): : 1243 - 1246
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