Synthesis and glass formation in the BaO-B2O3-BaCl2 system

被引：6
作者：
Brekhovskikh, M. N. [1 ]
Voronko, Yu. K. [2 ]
Dmitruk, L. N. [2 ]
Moiseeva, L. V. [2 ]
Petrova, O. B. [2 ]
Popov, A. V. [2 ]
Fedorov, V. A. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
来源：
INORGANIC MATERIALS | 2010年 / 46卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
CERAMICS;
D O I：
10.1134/S0020168510120216
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We have studied synthesis, glass formation, and crystallization processes in the oxychloride barium borate system BaO-B2O3-BaCl2 and determined the highest chlorine concentrations at which glasses can be prepared by mold casting for Ba: 2B ratios in the ranges 1.0-2.2 and 0.2-0.5. The process atmosphere has been shown to have a significant effect on the glass composition because of the chlorine release from the melt. We have determined the characteristic temperatures of the glasses and identified the crystalline phases that precipitate during cooling of the melt and heat treatment of the glasses.
引用
收藏
页码：1391 / 1395
页数：5
相关论文
共 11 条
  • [1] Optimisation of lithium borate-barium chloride glass-ceramic thermal neutron imaging plates
    Appleby, G. A.
    Vontobel, P.
    [J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2008, 594 (02) : 253 - 256
  • [2] Structure and photostimulated luminescent properties of Eu-doped M2BaX4 (M=Cs, Rb; X=Br, Cl)
    Appleby, GA
    Edgar, A
    Williams, GVM
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 96 (11) : 6281 - 6285
  • [3] Fluorescence and Judd-Ofelt analysis of Nd3+ ions in oxyfluoride glass ceramics containing CaF2 nanocrystals
    Chen, Daqin
    Wang, Yuansheng
    Yu, Yunlong
    Ma, En
    Liu, Feng
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 68 (02) : 193 - 200
  • [4] Fedorov PP, 2002, RUSS J INORG CHEM+, V47, P1042
  • [5] Crystallisation effects on rare earth dopants in oxyfluoride glass ceramics
    Goutaland, F
    Jander, P
    Brocklesby, WS
    Dai, GJ
    [J]. OPTICAL MATERIALS, 2003, 22 (04) : 383 - 390
  • [6] GREENBLATT S, 1967, PHYS CHEM GLASSES, V8, P190
  • [7] Physical properties of barium borate glasses determined over a wide range of compositions
    Kapoor, S
    George, HB
    Betzen, A
    Affatigato, M
    Feller, S
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 270 (1-3) : 215 - 222
  • [8] KIPRIANOV AA, 2006, FIZ KHIM STEKLA, V32, P3
  • [9] Rare-earth doped oxyfluoride glass-ceramics and fluoride ceramics: Synthesis and optical properties
    Mortier, M.
    Bensalah, A.
    Dantelle, G.
    Patriarche, G.
    Vivien, D.
    [J]. OPTICAL MATERIALS, 2007, 29 (10) : 1263 - 1270
  • [10] Structure and crystallization behavior of glasses in the BaO-B2O3-Al2O3 system
    Pernice, P
    Esposito, S
    Aronne, A
    Sigaev, VN
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 258 (1-3) : 1 - 10
12