A luminescent metal-organic framework with an open cubic cage and eight-coordinate cadmium nodes

被引:4
作者
Wang ChuanFeng [1 ,2 ]
Zhang ZhengXing [1 ]
Zhang LiLi [1 ]
Li FuYou [1 ]
Zhou XiGeng [1 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Taizhou Coll, Dept Chem, Linhai 317000, Peoples R China
基金
中国国家自然科学基金;
关键词
framework; eight-coordinate cadmium; cubic cage; fluorescence; pamoic acid; COORDINATION POLYMERS; MOLECULAR SQUARES; COMPLEX; ARCHITECTURES; LIGANDS; PORES;
D O I
10.1007/s11426-010-4098-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly of cadmium ions and the rigid bridging ligand 4,4'-methylenebis(3-hydroxy-2-naphthoic acid) (pamoic acid, H(4)PA) leads to a one-dimensional metal organic framework with open cube-like M-2(H(2)PA)(2) cages within its backbone, and exhibiting interesting yellow fluorescence.
引用
收藏
页码:2079 / 2082
页数:4
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