Aluminum complexes with sulfide-linked bis(phenolato) ligands:: Unusual structure and reactivity of the methyl bis(phenolato) complex "[Al(tbmp)Me]" (tbmp=2,2′-thiobis(6-tert-butyl-4-methylphenolato))

被引：20

作者：

Braune, W ^{[1
]}

Ma, HY ^{[1
]}

Spaniol, TP ^{[1
]}

Okuda, J ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52056 Aachen, Germany

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 08期

关键词：

D O I：

10.1021/om049067b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trialkylaluminum complexes, AIR(3) (R = Me, Et), reacted with the sulfide-bridged his(phenol) tbmpH(2) (tbmpH(2) = 2,2'-thiobis(6-tert-butyl-4-methylphenol)) in a 1:1 ratio to give monoalkyl compounds of the composition "[Al(tbmp)R]" with an unsymmetrical dinuclear structure with both six- and four-coordinate aluminum centers in the solid state. The reaction of 2 equiv of tbmpH(2) gave [Al(tbmp)(tbmpH)], which could be deprotonated with triethylamine to give [NEt3H] [Al(tbmp)(2)]. Upon reaction of [Al(tbmp)R](2) with Lewis bases L (L = Et2O, THF, propylene oxide), monomeric, five-coordinate adducts [Al(tbmp)R(L)] were formed, while 2-propanol gave the dinuclear complex [Al(tbmp)(mu-(OPr)-Pr-i)](2).

引用

页码：1953 / 1958

页数：6

共 101 条

[1] Mono(cyclopentadienyl)titanium complexes containing a sulfide-bridged bis(phenolato) ligand.: Molecular structure of Ti{2,2′-S(OC6H2-4-Me-6-tBu)2}(η5-C5-H5)Cl [J].

Amor, F ;

Fokken, S ;

Kleinhenn, T ;

Spaniol, TP ;

Okuda, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 621 (1-2) :3-9

[2] Molecular design of single site catalyst precursors for the ring-opening polymerization of cyclic ethers and esters. 2. Can ring-opening polymerization of propylene oxide occur by a cis-migratory mechanism? [J].

Antelmann, B ;

Chisholm, MH ;

Iyer, SS ;

Huffman, JC ;

Navarro-Llobet, D ;

Pagel, M ;

Simonsick, WJ ;

Zhong, WQ .

MACROMOLECULES, 2001, 34 (10) :3159-3175

[3] Symmetric and asymmetric samarium alkoxide derivatives of bridging sulfur biphenolate and binaphtholate ligands; synthetic, structural, and catalytic studies [J].

Arnold, PL ;

Natrajan, LS ;

Hall, JJ ;

Bird, SJ ;

Wilson, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 647 (1-2) :205-215

[4] TRIMETALLIC ALUMINUM AND GALLIUM ALKYL COMPLEXES WITH TETRADENTATE (N2O2) LIGANDS [J].

ATWOOD, DA ;

RUTHERFORD, D .

ORGANOMETALLICS, 1995, 14 (08) :3988-3995

[5] THE USE OF TETRADENTATE (N2O2) LIGANDS TO FORM MONOMERIC, TRIMETALLIC ALUMINUM COMPLEXES [J].

ATWOOD, DA ;

JEGIER, JA ;

MARTIN, KJ ;

RUTHERFORD, D .

ORGANOMETALLICS, 1995, 14 (03) :1453-1460

[6] CATIONIC ALUMINUM COMPOUNDS WITH POTENTIAL RELEVANCE TO LEWIS-ACID CATALYSIS [J].

ATWOOD, DA ;

JEGIER, JA ;

RUTHERFORD, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (25) :6779-6780

[7] Use of the salan ligands to form bimetallic aluminum complexes [J].

Atwood, DA ;

Remington, MP ;

Rutherford, D .

ORGANOMETALLICS, 1996, 15 (22) :4763-4769

[8] Interaction of the bifunctional Lewis acid 1,2-bis(chloromercurio)tetrafluorobenzene with aldehydes, nitriles, and epoxides [J].

Beckwith, JD ;

Tschinkl, M ;

Picot, A ;

Tsunoda, M ;

Bachman, R ;

Gabbaï, FP .

ORGANOMETALLICS, 2001, 20 (14) :3169-3174

[9] Recent results on rare B decays from BaBar and BELLE [J].

Brau, B .

NUCLEAR PHYSICS B-PROCEEDINGS SUPPLEMENTS, 2003, 115 :67-71

[10] An efficient method for controlled propylene oxide polymerization: The significance of bimetallic activation in aluminum Lewis acids [J].

Braune, W ;

Okuda, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :64-68

← 1 2 3 4 5 6 7 8 9 10 →