Suzuki-Miyaura reaction in water, conducted by employing an amphiphilic dendritic phosphine-palladium catalyst: a positive dendritic effect on chemical yield

被引:43
作者
Hattori, Hatsuhiko [1 ]
Fujita, Ken-ichi [1 ]
Muraki, Takahito [1 ]
Sakaba, Ai [1 ]
机构
[1] AIST, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1016/j.tetlet.2007.07.062
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of amphiphilic dendritic ligands with a phosphine core was synthesized by use of tris(4-hydroxyphenyl)phosphine oxide and poly(benzyl ether) dendron. The corresponding phosphine-palladium core dendrimers were applied as a catalyst to an aqueous-media Suzuki-Miyaura reaction. A positive dendritic effect on chemical yields of cross-coupling products was observed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6817 / 6820
页数:4
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