Structure, Properties and Applications of Two-Dimensional Hexagonal Boron Nitride

被引：553

作者：

Roy, Soumyabrata ^{[1
]}

Zhang, Xiang ^{[1
]}

Puthirath, Anand B. ^{[1
]}

Meiyazhagan, Ashokkumar ^{[1
]}

Bhattacharyya, Sohini ^{[1
]}

Rahman, Muhammad M. ^{[1
]}

Babu, Ganguli ^{[1
]}

Susarla, Sandhya ^{[2
]}

Saju, Sreehari K. ^{[1
]}

Tran, Mai Kim ^{[1
]}

Sassi, Lucas M. ^{[1
]}

Saadi, M. A. S. R. ^{[1
]}

Lai, Jiawei ^{[1
]}

Sahin, Onur ^{[1
]}

Sajadi, Seyed Mohammad ^{[1
]}

Dharmarajan, Bhuvaneswari ^{[1
]}

Salpekar, Devashish ^{[1
]}

Chakingal, Nithya ^{[1
]}

Baburaj, Abhijit ^{[1
]}

Shuai, Xinting ^{[1
]}

Adumbumkulath, Aparna ^{[1
]}

Miller, Kristen A. ^{[1
]}

Gayle, Jessica M. ^{[1
]}

Ajnsztajn, Alec ^{[1
]}

Prasankumar, Thibeorchews ^{[1
]}

Harikrishnan, Vijay Vedhan Jayanthi ^{[1
]}

Ojha, Ved ^{[1
]}

Kannan, Harikishan ^{[1
]}

Khater, Ali Zein ^{[1
]}

Zhu, Zhenwei ^{[1
]}

Iyengar, Sathvik Ajay ^{[1
]}

da Silva Autreto, Pedro Alves ^{[1
,3
]}

Oliveira, Eliezer Fernando ^{[1
,4
,5
]}

Gao, Guanhui ^{[1
]}

Birdwell, A. Glen ^{[6
]}

Neupane, Mahesh R. ^{[6
]}

Ivanov, Tony G. ^{[6
]}

Taha-Tijerina, Jaime ^{[1
,7
,8
]}

Yadav, Ram Manohar ^{[1
,9
]}

Arepalli, Sivaram ^{[1
]}

Vajtai, Robert ^{[1
]}

Ajayan, Pulickel M. ^{[1
]}

机构：

[1] Rice Univ, Dept Mat Sci & NanoEngn, 6100 Main St, Houston, TX 77005 USA

[2] Lawrence Berkeley Natl Lab, Mat Sci Div, 1 Cyclotron Rd, Berkeley, CA 94720 USA

[3] Fed Univ ABC UFABC, Ctr Nat & Human Sci, Av Estados 5001, BR-09210580 Santo Andre, SP, Brazil

[4] State Univ Campinas UNICAMP, Appl Phys Dept, BR-13083859 Campinas, SP, Brazil

[5] State Univ Campinas UNICAMP, Ctr Computat Engn & Sci CCES, BR-13083859 Campinas, SP, Brazil

[6] US Army Res Lab, Combat Capabil Dev Command, 2800 Powder Mill Rd, Adelphi, MD 20783 USA

[7] Univ Monterrey, Engn Dept, Av Ignacio Morones Prieto 4500 Pte, Monterrey 66238, Nuevo Leon, Mexico

[8] Univ Texas Rio Grande Valley, Dept Mfg & Ind Engn, Brownsville, TX 78520 USA

[9] VSSD Coll, Dept Phys, Kanpur 208002, Uttar Pradesh, India

来源：

ADVANCED MATERIALS | 2021年 / 33卷 / 44期

关键词：

2D materials; heterostructures; hexogonal boron nitride; insulators; nanoelectronic devices; CHEMICAL-VAPOR-DEPOSITION; ENHANCED THERMAL-CONDUCTIVITY; LARGE-SCALE SYNTHESIS; DER-WAALS HETEROSTRUCTURES; LIQUID-PHASE EXFOLIATION; SINGLE-PHOTON EMISSION; LARGE-AREA; MECHANICAL-PROPERTIES; H-BN; FEW-LAYER;

D O I：

10.1002/adma.202101589

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexagonal boron nitride (h-BN) has emerged as a strong candidate for two-dimensional (2D) material owing to its exciting optoelectrical properties combined with mechanical robustness, thermal stability, and chemical inertness. Super-thin h-BN layers have gained significant attention from the scientific community for many applications, including nanoelectronics, photonics, biomedical, anti-corrosion, and catalysis, among others. This review provides a systematic elaboration of the structural, electrical, mechanical, optical, and thermal properties of h-BN followed by a comprehensive account of state-of-the-art synthesis strategies for 2D h-BN, including chemical exfoliation, chemical, and physical vapor deposition, and other methods that have been successfully developed in recent years. It further elaborates a wide variety of processing routes developed for doping, substitution, functionalization, and combination with other materials to form heterostructures. Based on the extraordinary properties and thermal-mechanical-chemical stability of 2D h-BN, various potential applications of these structures are described.

引用

页数：48

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