Improving cubic equations of state for heavy reservoir fluids and critical region

It is shown that by considering the "b" parameter in a cubic equation of state (EOS) as acentric factor/temperature-dependent, liquid densities especially for heavy compounds and the region near the critical point can be estimated more accurately. The proposed equation can also be used for accurate estimation of critical compressibility factors of different compounds. Although the method is applied to Peng-Robinson equation of stale (PR-EOS), ii can be used for any other cubic equation of state. The proposed method is particularly useful for phase equilibrium calculations of reservoir fluids. The proposed equation requires critical temperature, critical pressure and acentric factor as the input parameters. The proposed equation of state estimates properties of liquids, vapor-pressure and critical compressibility factors with greater accuracy for pure compounds and mixtures as well as light and heavy compounds found in reservoir fluids.