Topological defects at octahedral tilting plethora in bi-layered perovskites

被引:50
|
作者
Huang, Fei-Ting [1 ,2 ]
Gao, Bin [1 ,2 ]
Kim, Jae-Wook [1 ,2 ]
Luo, Xuan [3 ,4 ]
Wang, Yazhong [1 ,2 ]
Chu, Ming-Wen [5 ]
Chang, Chung-Kai [6 ]
Sheu, Hwo-Shuenn [6 ]
Cheong, Sang-Wook [1 ,2 ,3 ,4 ]
机构
[1] Rutgers State Univ, Rutgers Ctr Emergent Mat, Piscataway, NJ 08854 USA
[2] Rutgers State Univ, Dept Phys & Astron, Piscataway, NJ 08854 USA
[3] Pohang Univ Sci & Technol, Lab Pohang Emergent Mat, Pohang, South Korea
[4] Pohang Univ Sci & Technol, Max Plank POSTECH Ctr Complex Phase Mat, Pohang, South Korea
[5] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei, Taiwan
[6] Natl Synchrotron Radiat Res Ctr, Hsinchu, Taiwan
关键词
DOMAIN-WALLS; FERROELECTRICITY; MANGANITES; CRYSTAL; LA2-XBAXCUO4; TRANSITIONS; PHYSICS; OXIDES; FILMS;
D O I
10.1038/npjquantmats.2016.17
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Oxygen octahedral distortions, including tilts/rotations, deformations and off-centring in (layered) perovskites, have the key role in their numerous functional properties. Near the polar-centrosymmetric phase boundary in bi-layered perovskite Ca3-xSrxTi2O7 with x approximate to 1, we found the presence of abundant topological eight-state vortex-antivortex pairs, associated with four oxygen octahedral tilts at domains and another four different oxygen octahedral tilts at domain walls. Our discovery opens a new revenue to unveil real-space topological defects associated with the possible vector choices in one specific lattice mode.
引用
收藏
页数:6
相关论文
共 50 条
  • [1] Topological defects at octahedral tilting plethora in bi-layered perovskites
    Fei-Ting Huang
    Bin Gao
    Jae-Wook Kim
    Xuan Luo
    Yazhong Wang
    Ming-Wen Chu
    Chung-Kai Chang
    Hwo-Shuenn Sheu
    Sang-Wook Cheong
    npj Quantum Materials, 1
  • [2] Dielectric Relaxation Mechanisms in Relaxor Bi-Layered Perovskites
    Pelaiz-Barranco, A.
    Gonzalez-Abreu, Y.
    FERROELECTRICS, 2012, 426 : 122 - 131
  • [3] Ferroelectric Instability and Dimensionality in Bi-Layered Perovskites and Thin Films
    Onodera, Akira
    Fukunaga, Masanori
    Takesada, Andmasaki
    ADVANCES IN CONDENSED MATTER PHYSICS, 2012, 2012
  • [4] Octahedral Tilting, Cation Ordering, And Hydrogen Bonding in Layered Hybrid Halide Perovskites
    Woodward, Patrick M.
    Holzapfel, Noah
    Liu, Tianyu
    Race, Joe
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2023, 79 : A180 - A180
  • [5] Bi-layered Composite Scaffold for Repair of the Osteochondral Defects
    Xu, Dongdong
    Cheng, Gu
    Dai, Jinhong
    Li, Zhi
    ADVANCES IN WOUND CARE, 2021, 10 (08) : 401 - 414
  • [6] EXPERIMENTAL STUDIES OF OCTAHEDRAL TILTING IN PEROVSKITES
    Howard, C. J.
    Kennedy, B. J.
    Chakoumakos, B. C.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 150 - 150
  • [7] Phase transitions in hybrid layered halide perovskites - Hydrogen bonding meets octahedral tilting
    Woodward, P. M.
    Holzapfel, N. P.
    Liu, T.
    Race, J.
    Milder, A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2021, 77 : C150 - C150
  • [8] Effect of defects and reinforcements on the mechanical behaviour of a bi-layered panel
    Wu, C. L.
    Zhang, L. L.
    Yin, H. M.
    PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2023, 479 (2271):
  • [9] Octahedral tilting instabilities in inorganic halide perovskites
    Bechtel, Jonathon S.
    Van der Ven, Anton
    PHYSICAL REVIEW MATERIALS, 2018, 2 (02):
  • [10] A biomimetic bi-layered tissue engineering scaffolds for osteochondral defects repair
    LIU KaiQiang
    LIU YanNan
    DUAN ZhiGuang
    MA XiaoXuan
    FAN DaiDi
    Science China(Technological Sciences), 2021, 64 (04) : 793 - 805