A new synthetic strategy to 2,3-diallyl-1,4-quinones via one-pot double Claisen rearrangement and retro Diels-Alder reaction

被引：7
作者：
Kotha, Sambasivarao [1 ]
Gunta, Rama [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 27-28期
关键词：
Claisen rearrangement; 2,3-Diallyl-1,4-quinones; Retro Diels-Alder reaction; Metathesis; RING-CLOSING METATHESIS; DIVERSITY-ORIENTED APPROACH; OLEFIN METATHESIS; KEY STEPS; NATURAL-PRODUCTS; DERIVATIVES; ROUTE; QUINONES; DESIGN;
D O I：
10.1016/j.tetlet.2016.05.101
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and an efficient synthetic strategy to 2,3-diallyl-1,4-quinone derivatives via a highly reliable and 100% atom economic reactions such as Diels-Alder (DA) reaction, Claisen rearrangement (CR), and retro Diels-Alder (rDA) reaction as key steps is reported. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3021 / 3023
页数：3
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