Evolution of hydrate habit and formation properties evolution during hydrate phase transition in fractured-porous medium

被引:14
作者
Bian, Hang [1 ,2 ]
Qin, Xuwen [3 ,4 ]
Luo, Wanjing [1 ]
Ma, Chao [3 ,4 ]
Zhu, Jian [5 ]
Lu, Cheng [2 ,3 ,7 ]
Zhou, Yingfang [1 ,6 ]
机构
[1] China Univ Geosci, Sch Energy Resources, Beijing 100083, Peoples R China
[2] Ctr Oil & Nat Gas Resource Explorat, China Geol Survey, Beijing 100083, Peoples R China
[3] Guangzhou Marine Geol Survey, China Geol Survey, Guangzhou 510075, Peoples R China
[4] Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China
[5] iRock Technol, Beijing 100094, Peoples R China
[6] Univ Aberdeen, Sch Engn, Aberdeen, Scotland
[7] Natl Engn Res Ctr Gas Hydrate Explorat & Dev, Guangzhou 511458, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrate Habit; Hydrate Morphology; Fractured-Porous Medium; Micro-CT; Seepage Capacity; NATURAL-GAS HYDRATE; MARINE-SEDIMENTS; METHANE-HYDRATE; NMR MEASUREMENTS; WAVE VELOCITY; PERMEABILITY; DECOMPOSITION; SAND; MICROTOMOGRAPHY; TOMOGRAPHY;
D O I
10.1016/j.fuel.2022.124436
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Natural gas hydrate, as an efficient and clean energy resource, are naturally distributed in porous and fractured porous medium. With the most recent development of advanced micro-scale imaging techniques, hydrate habits evolution, hydrate occurrences, and pore structure evolution as well as seepage characteristics during hydrate phase transition in porous hydrate-bearing sediments have been studied extensively at pore scale. However, there are few studies on gas hydrates in fractured-porous sediment. In this work, xenon hydrate phase transition experiment by excess-gas method is carried out in a fractured sandstone core with in-situ micro computed tomography (micro-CT) scanning to explore the evolution of hydrate habits and physical parameters of the host sediment. The results indicate that hydrate-bearing sediment is a dynamic equilibrium system as hydrate synthesis and decomposition occur simultaneously at each moment of hydrate phase transition induced by pressure change. The hydrate occurrences in fractured hydrate reservoirs include contiguous-sheet, clustered and isolated, which are slightly different from that of porous hydrate formation; and the contiguous-sheet hydrate is the occurrence that dominantly determines the seepage characteristics of fractured hydrate-bearing sediments. In addition, the logic diagram for hydrate growth paths in fractured-porous medium is presented for the first time. These findings are significant for detailed understanding of pore-scale hydrate distribution throughout phase transition process and provide theoretical basis for precise modeling of permeability in host sediments.
引用
收藏
页数:14
相关论文
共 91 条
[61]   Evaluation of drilling parameters in gas hydrate exploration wells [J].
Merey, Sukru .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2019, 172 :855-877
[62]  
Myerson A.S., 2001, HDB IND CRYSTALLIZAT, V2nd
[63]   Mathematica programs for the analysis of three-dimensional pore connectivity and anisotropic tortuosity of porous rocks using X-ray computed tomography image data [J].
Nakashima, Yoshito ;
Kamiya, Susumu .
JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 2007, 44 (09) :1233-1247
[64]   Mechanical properties of clathrate hydrates: status and perspectives [J].
Ning, Fulong ;
Yu, Yibing ;
Kjelstrup, Signe ;
Vlugt, Thijs J. H. ;
Glavatskiy, Kirill .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (05) :6779-6795
[65]   Quantification of gas hydrate saturation and morphology based on a generalized effective medium model [J].
Pan, Haojie ;
Li, Hongbing ;
Chen, Jingyi ;
Riedel, Michael ;
Holland, Melanie ;
Zhang, Yan ;
Cai, Shengjuan .
MARINE AND PETROLEUM GEOLOGY, 2020, 113
[66]   X-ray microtomography shows pore structure and tortuosity in alkali-activated binders [J].
Provis, John L. ;
Myers, Rupert J. ;
White, Claire E. ;
Rose, Volker ;
van Deventer, Jannie S. J. .
CEMENT AND CONCRETE RESEARCH, 2012, 42 (06) :855-864
[67]   Compressional and shear wave pre-stack analysis of gashydrate resources in the Makran Accretionary Prism [J].
Salehi, Ehsan ;
Javaherian, Abdolrahim ;
Pour, Majid Ataee ;
Khah, Nasser Keshavarz Faraj ;
Khoshdel, Hossein .
ENERGY EXPLORATION & EXPLOITATION, 2014, 32 (02) :369-388
[68]   Image processing of multiphase images obtained via X- ray microtomography: A review [J].
Schlueter, Steffen ;
Sheppard, Adrian ;
Brown, Kendra ;
Wildenschild, Dorthe .
WATER RESOURCES RESEARCH, 2014, 50 (04) :3615-3639
[69]   Methane hydrate induced permeability modification for multiphase flow in unsaturated porous media [J].
Seol, Yongkoo ;
Kneafsey, Timothy J. .
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH, 2011, 116
[70]   Phase transition from structure-H to structure-I in the methylcyclohexane plus xenon hydrate system [J].
Shimada, N ;
Sugahara, K ;
Sugahara, T ;
Ohgaki, K .
FLUID PHASE EQUILIBRIA, 2003, 205 (01) :17-23