Flame retardant polyurethane foams with starch unit

被引:16
作者
Lubczak, Renata [1 ]
Broda, Daniel [2 ]
Kus-Liskiewicz, Malgorzata [2 ]
Szczech, Dominik [3 ]
Bobko, Ewa [4 ]
Debska, Bernardetta [5 ]
Szpilyk, Marzena [1 ]
Lubczak, Jacek [1 ]
机构
[1] Rzeszow Univ Technol, Fac Chem, Al Powstancow Warszawy 6, PL-35959 Rzeszow, Poland
[2] Univ Rzeszow, Coll Nat Sci, Inst Biol & Biotechnol, Pigonia St 1, PL-35310 Rzeszow, Poland
[3] SoBiCo GmbH, D-55566 Bad Sobernheim, Germany
[4] Univ Rzeszow, Coll Nat Sci, Inst Phys, Pigonia St 1, PL-35959 Rzeszow, Poland
[5] Rzeszow Univ Technol, Dept Bldg Engn, Poznanska St 2, PL-35084 Rzeszow, Poland
关键词
Starch; Hydroxyalkylation; Polyols; Polyurethane foams; Flame retardants; Biodegradation; PROPYLENE-OXIDE; PHOSPHORUS;
D O I
10.1016/j.polymertesting.2021.107395
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Polyurethane foams with incorporated starch described in up to date literature have good functional properties except flame resistance. Their oxygen index falls within 19.3-20.5%, while flame rate is 2.25-12.50 mm/s. We have obtained and tested polyurethane foams with following flame retardants: melamine, and two phosphoric(V) acid esters: Fyrol PNX and Fyrol PCF. The functional properties of the flame retardant modified foams were compared with non-modified foams using horizontal flaming tests, determination of oxygen index and combustion in microcalorimeter. According to horizontal flaming tests all modified foams were self-extinguishing. The oxygen index of modified foams was within 22.9-24.4%. The foams could stand long-term heating at 150 degrees C temperature. Moreover, the polyurethane foams have a biodegradation potential.
引用
收藏
页数:11
相关论文
共 49 条
[1]  
Alfani R, 1998, J APPL POLYM SCI, V68, P739, DOI 10.1002/(SICI)1097-4628(19980502)68:5<739::AID-APP6>3.0.CO
[2]  
2-P
[3]  
[Anonymous], 606951110201402 PNEN
[4]  
[Anonymous], 2015, 13927 ENISO
[5]  
[Anonymous], 35822002 PNEN ISO PO
[6]  
[Anonymous], 2006, 45892 PNEN ISO POL E
[7]  
Brzozowski Z., 2001, Plast. Rev, V9, P65
[8]  
Cellular Plastics, 8441978 PNEN ISO POL
[9]  
Cellular Plastics, 27961986 PNEN ISO PO
[10]  
Cellular Plastics and Rubbers, 8452000 PNEN ISO POL