Kinetics of the CN+CH2CO and NCO+CH2CO reactions

被引：21
作者：
Edwards, MA [1 ]
Hersberger, JF [1 ]
机构：
[1] N Dakota State Univ, Dept Chem, Fargo, ND 58105 USA
来源：
CHEMICAL PHYSICS | 1998年 / 234卷 / 1-3期
关键词：
kinetics; ketene; radical reactions;
D O I：
10.1016/S0301-0104(98)00174-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The CN + CH2CO and NCO + CH2CO reactions were studied over the temperature ranges 296-567 K and 296-556 K, respectively, using time-resolved infrared diode laser absorption and visible laser-induced fluorescence spectroscopy. The total rate constant data were fit to the following expressions: k(1)(CN + CH2CO) = (2.37 +/- 0.5) X 10(-11) exp[552.6 +/- 97/T] and k(2)(NCO + CH2CO) = (1.71 +/- 0.27) X 10(-12) exp[713.2 +/- 56/T] cm(3) molecule(-1) s(-1). Detection and quantification of CO product yields suggests that an addition-elimination mechanism producing CH2CN + CO or CH2NCO + CO dominates these reactions, and that hydrogen abstraction to produce HCN + HCCO or HNCO + HCCO is a minor or negligible product channel. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：231 / 237
页数：7
相关论文
共 50 条
  • [31] Mechanism of the reaction H+CH2CO: G2 calculation
    Jun, M
    Feng, WL
    Li, HY
    Liu, KH
    Pu, M
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2004, 20 (05) : 483 - 487
  • [32] A Study on the Kinetics of the Catalytic Reforming Reaction of CH4 with CO2: Determination of the Reaction Order
    Chunyang Ji
    [J]. Journal of Natural Gas Chemistry, 2003, (03) : 201 - 204
  • [33] Kinetics of the CN + CS2 and CN + SO2 Reactions
    Feng, Wenhui
    Hershberger, John F.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (03) : 286 - 290
  • [34] Influence of the carbon chain length of a sulfate-based surfactant on the formation of CO2, CH4 and CO2-CH4 gas hydrates
    Dicharry, Christophe
    Diaz, Joseph
    Torre, Jean-Philippe
    Ricaurte, Marvin
    [J]. CHEMICAL ENGINEERING SCIENCE, 2016, 152 : 736 - 745
  • [35] Potential Energy Surfaces for the Reactions of HO2 Radical with CH2O and HO2 in CO2 Environment
    Masunov, Artem E.
    Atlanov, Arseniy A.
    Vasu, Subith S.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (39) : 7681 - 7688
  • [36] CO2/CH4 hydrate formation from CO2/CH4 liquid mixtures: A key to CO2 sequestration in marine depleted hydrate and shallow gas reservoirs via liquid CO2 injection
    Yao, Yuanxin
    Niu, Mengya
    Zi, Mucong
    Ye, Hongyu
    Duan, Jun
    Chen, Daoyi
    [J]. CHEMICAL ENGINEERING JOURNAL, 2025, 509
  • [37] Adsorption kinetics and thermodynamics of CO2and CH4on activated carbon modified by acetic acidAdsorptionskinetik und Thermodynamik von CO2und CH4auf Aktivkohle modifiziert durch Essigsaure
    Song, X.
    Wang, L.
    Gong, J.
    Zeng, Y.
    Zhan, X.
    Ni, Z.
    [J]. MATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, 2020, 51 (07) : 957 - 969
  • [38] Tunneling Enhancement of the Gas-Phase CH + CO2 Reaction at Low Temperature
    Nunez-Reyes, Dianailys
    Hickson, Kevin M.
    Loison, Jean-Christophe
    Spada, Rene F. K.
    Vichietti, Rafael M.
    Machado, Francisco B. C.
    Haiduke, Roberto L. A.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 124 (51) : 10717 - 10725
  • [39] CH2Cl and CHCl2 Radical Chemistry: The Formation by the Reactions CH3Cl + F and CH2Cl2 + F and the Destruction by the Reactions CH2Cl + O and CHCl2 + O
    Hold, M.
    Hoyermann, K.
    Morozov, I.
    Zeuch, T.
    [J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2009, 223 (4-5): : 409 - 426
  • [40] Computational Study of the Rate Coefficients for the Reactions of NO2 with CH3NHNH, CH3NNH2, and CH2NHNH2
    Kanno, Nozomu
    Tani, Hiroumi
    Daimon, Yu
    Terashima, Hiroshi
    Yoshikawa, Norihiko
    Koshi, Mitsuo
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28) : 7659 - 7667
12345