Cyclometalated rhodium(III) complex with phen-dione ligand

被引：20
作者：
Mansouri, Ghobad
Rezvani, Ali R.
Hadadzadeh, Hassan [1 ]
Khavasi, Hamid Reza
Saravani, Hamideh
机构：
[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
[2] Univ Sistan & Baluchestan, Dept Chem, Zahedan, Iran
[3] Shahid Beheshti Univ, Dept Chem, Tehran, Iran
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 17期
关键词：
Rh(III) complex; cyclometalated complex; 1,10-phenanthroline-5,6-dione; 2-phenylpyridine; crystal structure; cyclic voltammetry;
D O I：
10.1016/j.jorganchem.2007.05.043
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel cyclometalated Rh(III) complex, [Rh(phpy-K-2 N, C-2 ')2(phen-dione)]PF6, where phpy-K-2 N, C-2 ' is pyridine-2-yl-2-phenyl and phen-dione is 1,10-phenanthroline-5,6-dione has been prepared and characterized by elemental analysis, IR, H-1 NMR, and electronic absorption spectroscopies, cyclic voltammetry, and X-ray crystallography. The crystal structure of [Rh(phpy-K-2 N C-2 ')2(phen-dione)]PF6 center dot CH3CN shows that the coordination geometry around the Rh(111) is a distorted octahedron, with bite angles of 76.13 degrees-81.09 degrees for all three bidentate ligands. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：3810 / 3815
页数：6
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