Enhanced Ferromagnetism and Microwave Dielectric Properties of Bi0.95Y0.05FeO3 Nanocrystals

被引:17
作者
Hou Zhi-Ling [1 ]
Zhou Hai-Feng [1 ]
Yuan Jie [2 ]
Kang Yu-Qing [2 ]
Yang Hui-Jing [2 ]
Jin Hai-Bo [2 ]
Cao Mao-Sheng [2 ]
机构
[1] Beijing Univ Chem Technol, Sch Sci, Beijing 100029, Peoples R China
[2] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
关键词
MULTIFERROIC BIFEO3; MAGNETIC-PROPERTIES; DOPED BIFEO3; TEMPERATURE; COATINGS; BEHAVIOR;
D O I
10.1088/0256-307X/28/3/037702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Bi0.95Y0.05FeO3 nanocrystals are synthesized by a hydrothermal method, and are crystallized in a rhombohedrally distorted perovskite BiFeO3 structure in the R3c space, with compressive lattice distortion induced by the Y substitution at Bi sites from XRD study. Compared with BiFeO3 gained under similar conditions, the magnetic properties are greatly enhanced, with saturate magnetization of 2.3 emu/g at room temperature. Microwave dielectric properties of Bi0.95Y0.05FeO3 nanocrystals are investigated in the range of 2-18 GHz. The Y substitution results in the increase of permeability and decrease of permittivity, which are attributed to the enhanced spin relaxation of domain wall motion and the weakened electron-relaxation caused by decreasing Fe2+, respectively. The changes for microwave dielectric response could lead to the excellent microwave absorption due to the improvement of the impedance match between BiFeO3 and air.
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页数:4
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