Heterogeneous copper-catalyzed coupling of amines: a possible way for the preparation of imines

被引：15
|
作者：
Magyar, Agnes [1 ]
Hell, Zoltan [1 ]
机构：
[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, Muegyet Rkp 3, H-1111 Budapest, Hungary
来源：
MONATSHEFTE FUR CHEMIE | 2016年 / 147卷 / 09期
关键词：
Imines; Amines; Copper; 4-angstrom molecular sieves; Heterogeneous catalysis; AEROBIC OXIDATION; SECONDARY-AMINES; NEAT CONDITIONS; SCHIFF-BASES; BULK GOLD; ALCOHOLS; TIO2; PHOTOCATALYSIS; BENZYLAMINES; DERIVATIVES;
D O I：
10.1007/s00706-016-1784-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper(II) on 4- molecular sieves is an efficient catalyst for the preparation of imines from benzylamines under simple reaction conditions. No oxidative atmosphere or oxidizing agents are required. Preparative experiments showed that no aldehyde intermediate can be detected even under ambient atmospheric conditions.
引用
收藏
页码：1583 / 1589
页数：7
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