Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

被引：35

作者：

Ema, Tadashi ^{[1
]}

Tanida, Daisuke ^{[1
]}

Matsukawa, Tatsuya ^{[1
]}

Sakai, Takashi ^{[1
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biochem, Okayama 7008530, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 08期

关键词：

D O I：

10.1039/b718763g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

引用

页码：957 / 959

页数：3

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