Biochar from the Thermochemical Conversion of Orange (Citrus sinensis) Peel and Albedo: Product Quality and Potential Applications

被引:76
作者
Adeniyi, Adewale George [1 ]
Ighalo, Joshua O. [1 ]
Onifade, Damilola Victoria [1 ]
机构
[1] Univ Ilorin, Fac Engn & Technol, Dept Chem Engn, PMB 1515, Ilorin, Nigeria
来源
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY | 2020年 / 3卷 / 02期
关键词
Orange peels; Orange albedo; Bio-char; Characterisation; Thermochemical conversion; SUGAR-CANE BAGASSE; ACTIVATED CARBON; CHEMICAL-CHARACTERIZATION; AQUEOUS-SOLUTION; BIO-OIL; WASTE; BIOMASS; CARBONIZATION; ADSORPTION; PYROLYSIS;
D O I
10.1007/s42250-020-00119-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Orange (Citrus sinensis) is a popular fruit in west Africa that generates residues such as peels (OP) and albedo (OA) from its consumption. In this study, the biochar obtained from the char-optimised thermochemical conversion of orange peels and albedo were evaluated. The products obtained was characterised using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) and Branueur-Emmett-Teller (BET) Analyses and potential applications were discussed. FTIR analysis revealed similar spectra for both samples and possessing polar groups such as alcohol, esters, ketones, aldehydes, carboxylic, ether and phenols which are characteristic of low-temperature biochar. The EDS analysis showed that OP biochar possess higher carbon content than OA biochar whilst the latter contains more inorganic elements. SEM analysis revealed that OP biochar possess a smooth surface as compared to the highly convoluted surface of the OA biochar. BET analysis revealed that the surface area was 352.5 m(2) g(-1) and 356.3 m(2) g(-1) for OP and OA biochar, respectively. Several key conclusions on the potential applications were proposed based on the analytical findings and these include soil amendment, adsorbents and as catalysts.
引用
收藏
页码:439 / 448
页数:10
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