[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]bis(thiocyanato-κN)cadmium(II)

被引：1

作者：

Zheng, Lu Yi ^{[1
]}

Chi, Yan Hui ^{[2
]}

机构：

[1] Univ Jinan, Coll Chem & Chem Engn, Jinan 250022, Peoples R China

[2] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536810051275

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cd(NCS)(2)(C22H20N6)], the Cd-II ion is in a CdN6 coordination geometry which is intermediate between octahedral and trigonal-prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)degrees. In the crystal, there is a pi-pi stacking interaction involving two symmetry-related pyrazole rings, with a centroid-centroid distance of 3.664 (3) angstrom. In addition, there is a relatively short intermolecular contact between C atoms [C center dot center dot center dot C = 3.399 (6) angstrom] involving symmetry-related pyridine rings along the a axis.

引用

页码：M68 / U762

页数：12