Domino Reactions Triggered by Hydroformylation

被引:16
作者
Petricci, Elena [1 ]
Cini, Elena [1 ]
机构
[1] Univ Siena, Dipartimento Biotecnol Chim & Farm, I-53100 Siena, Italy
来源
HYDROFORMYLATION FOR ORGANIC SYNTHESIS | 2013年 / 342卷
关键词
Cyclohydrocarbonylation; Domino reactions; Hydroaminomethylation; Hydroformylation; Microwaves; LONG-CHAIN ALKENES; HIGHLY REGIOSELECTIVE HYDROAMINOMETHYLATION; RHODIUM-CATALYZED HYDROFORMYLATION; MICROWAVE-ASSISTED HYDROGENATION; SELECTIVE HYDROAMINOMETHYLATION; EFFICIENT SYNTHESES; INTERNAL ALKENES; TRANSITION-METAL; AMINO-ACIDS; OLEFINS;
D O I
10.1007/128_2013_463
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
HF reaction represents a selective method for the synthesis of aldehydes starting from alkenes. Because of versatile aldehydes reactivity, it is possible to perform different domino protocols based on contemporary HF, including Michael's reaction, reductive amination, cyclopropanation, lactonization, and many others. This overview reports on the last 5 years' results obtained on this field.
引用
收藏
页码:117 / 149
页数:33
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