Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4

被引:194
作者
Hassan, H. [1 ]
Hameed, B. H. [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Penang, Malaysia
关键词
Fe-ball clay; Reactive Blue 4; Heterogeneous Fenton; Decolorization; WET PEROXIDE OXIDATION; HYDROGEN-PEROXIDE; PILLARED CLAY; DEGRADATION; WATER; CU(II); PHENOL; DYES;
D O I
10.1016/j.cej.2011.04.040
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Decolorization of anthraquinone dye Reactive Blue 4 (RB4) in an aqueous solution was investigated by using Fe-ball clay (Fe-BC) as heterogeneous catalyst. The best reacting conditions were found to be 0.80 wt.% of iron ions loading on ball clay (BC) when the dosage of catalyst is 5.0 g L-1 with initial pH of 3.0. [H2O2](0) of 8 mM, [RB4](0) of 50 mg L-1 at temperature 30 degrees C. Under these conditions, 99% decolorization efficiency of RB4 was achieved within 140 min reaction time. The results indicated that Fe-BC has proven to be a superior heterogeneous catalyst for decolorization of RB4 in an aqueous solution. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:912 / 918
页数:7
相关论文
共 31 条
  • [21] Ramamurthi V., 2009, Modern Applied Science, V3, P37
  • [22] Fenton-like oxidation of Orange II solutions using heterogeneous catalysts based on saponite clay
    Ramirez, J. Herney
    Costa, Carlos A.
    Madeira, Luis M.
    Mata, G.
    Vicente, Miguel A.
    Rojas-Cervantes, M. L.
    Lopez-Peinado, A. J.
    Martin-Aranda, R. M.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 71 (1-2) : 44 - 56
  • [23] The effect of dehydroxylation/amorphization degree on pozzolanic activity of kaolinite
    Shvarzman, A
    Kovler, K
    Grader, GS
    Shter, GE
    [J]. CEMENT AND CONCRETE RESEARCH, 2003, 33 (03) : 405 - 416
  • [24] Degradation of azo dye Amido black 10B in aqueous solution by Fenton oxidation process
    Sun, Jian-Hui
    Sun, Sheng-Peng
    Wang, Guo-Liang
    Qiao, Li-Ping
    [J]. DYES AND PIGMENTS, 2007, 74 (03) : 647 - 652
  • [25] TARR M.A., 2003, ENV SCI POLLUTION CO, P165
  • [26] Xu HY, 2009, B KOREAN CHEM SOC, V30, P2249
  • [27] Schorl: A novel catalyst in mineral-catalyzed Fenton-like system for dyeing wastewater discoloration
    Xu, Huan-yan
    Prasad, Murari
    Liu, Yu
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2009, 165 (1-3) : 1186 - 1192
  • [28] Yariv S., 2002, Organo-clay complexes and interactions
  • [29] Catalytic wet peroxide oxidation of phenol with a Fe/active carbon catalyst
    Zazo, J. A.
    Casas, J. A.
    Mohedano, A. F.
    Rodriguez, J. J.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 65 (3-4) : 261 - 268
  • [30] Degradation of CI Acid Orange 7 by ultrasound enhanced heterogeneous Fenton-like process
    Zhang, Hui
    Fu, Hao
    Zhang, Daobin
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2009, 172 (2-3) : 654 - 660