Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4

被引:197
作者
Hassan, H. [1 ]
Hameed, B. H. [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Penang, Malaysia
关键词
Fe-ball clay; Reactive Blue 4; Heterogeneous Fenton; Decolorization; WET PEROXIDE OXIDATION; HYDROGEN-PEROXIDE; PILLARED CLAY; DEGRADATION; WATER; CU(II); PHENOL; DYES;
D O I
10.1016/j.cej.2011.04.040
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Decolorization of anthraquinone dye Reactive Blue 4 (RB4) in an aqueous solution was investigated by using Fe-ball clay (Fe-BC) as heterogeneous catalyst. The best reacting conditions were found to be 0.80 wt.% of iron ions loading on ball clay (BC) when the dosage of catalyst is 5.0 g L-1 with initial pH of 3.0. [H2O2](0) of 8 mM, [RB4](0) of 50 mg L-1 at temperature 30 degrees C. Under these conditions, 99% decolorization efficiency of RB4 was achieved within 140 min reaction time. The results indicated that Fe-BC has proven to be a superior heterogeneous catalyst for decolorization of RB4 in an aqueous solution. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:912 / 918
页数:7
相关论文
共 31 条
[11]   The sonochemical degradation of azobenzene and related azo dyes: Rate enhancements via Fenton's reactions [J].
Joseph, JM ;
Destaillats, H ;
Hung, HM ;
Hoffmann, MR .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (02) :301-307
[12]   Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst [J].
Kasiri, M. B. ;
Aleboyeh, H. ;
Aleboyeh, A. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 84 (1-2) :9-15
[13]   Advanced oxidation of natural organic matter using hydrogen peroxide and iron-coated pumice particles [J].
Kitis, M. ;
Kaplan, S. S. .
CHEMOSPHERE, 2007, 68 (10) :1846-1853
[14]   Comparison of surface properties between kaolin and metakaolin in concentrated lime solutions [J].
Konan, K. L. ;
Peyratout, C. ;
Smith, A. ;
Bonnet, J. -P. ;
Rossignol, S. ;
Oyetola, S. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 339 (01) :103-109
[15]   Adsorption and thermodynamic studies of Cu(II) and Zn(II) on organofunctionalized-kaolinite [J].
Lima Guerra, Denis ;
Airoldi, Claudio ;
de Sousa, Kaline S. .
APPLIED SURFACE SCIENCE, 2008, 254 (16) :5157-5163
[16]   Fe (III) supported on resin as effective catalyst for the heterogeneous oxidation of phenol in aqueous solution [J].
Liou, RM ;
Chen, SH ;
Hung, MY ;
Hsu, CS ;
Lai, JY .
CHEMOSPHERE, 2005, 59 (01) :117-125
[17]   Heterogeneous catalytic wet peroxide oxidation systems for the treatment of an industrial pharmaceutical wastewater [J].
Melero, J. A. ;
Martinez, F. ;
Botas, J. A. ;
Molina, R. ;
Pariente, M. I. .
WATER RESEARCH, 2009, 43 (16) :4010-4018
[18]   Synthesis, characterisation and catalytic evaluation of iron-manganese mixed oxide pillared clay for VOC decomposition reaction [J].
Mishra, T. ;
Mohapatra, P. ;
Parida, K. M. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 79 (03) :279-285
[19]   Utilization of ball clay adsorbents for the removal of crystal violet dye from aqueous solution [J].
Monash, P. ;
Niwas, Ram ;
Pugazhenthi, G. .
CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY, 2011, 13 (01) :141-151
[20]   Decolourisation of Reactive Orange 4 by Fenton and photo-Fenton oxidation technology [J].
Muruganandham, M ;
Swaminathan, M .
DYES AND PIGMENTS, 2004, 63 (03) :315-321