Surface-Functionalized Silicon Nanoparticles as Anode Material for Lithium-Ion Battery

被引：83
作者：
Jiang, Sisi [1 ,3 ]
Hu, Bin [1 ]
Sahore, Ritu [1 ]
Zhang, Linghong [1 ]
Liu, Haihua [2 ]
Zhang, Lu [1 ]
Lu, Wenquan [1 ]
Zhao, Bin [3 ]
Zhang, Zhengcheng [1 ]
机构：
[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
[2] Argonne Natl Lab, Ctr Nanoscale Mat, Lemont, IL 60439 USA
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 51期
关键词：
nanosilicon particles; silicon anode; silanization reaction; surface modification; epoxy-functionalized surface; lithium-ion battery; ELECTROCHEMICAL PERFORMANCE; POLYACRYLIC-ACID; CARBOXYMETHYL CELLULOSE; NANOSTRUCTURED SILICON; AQUEOUS SLURRIES; COMPOSITE ANODE; POLYMER BINDERS; SI; ELECTRODES; STABILITY;
D O I：
10.1021/acsami.8b17729
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
An epoxy group was successfully attached to the surface of silicon nanoparticle (SiNPs) via a silanization reaction between silanol-enriched SiNPs and functional silanes. The epoxy-functionalized SiNPs showed a much improved cell performance compared with the pristine SiNPs because of the increased stability with electrolyte and the formation of a covalent bond between the epoxy group and the polyacrylic acid binder. Furthermore, the anode laminate made from epoxy-SiNPs showed much enhanced adhesion strength. Post-test analysis shed light on how the epoxy-functional group affects the physical and electrochemical properties of the SiNP anode.
引用
收藏
页码：44924 / 44931
页数：8
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