Direct use of 1,3-dienes for the allylation of ketones via catalytic hydroindation

被引：1

作者：

Suzuki, Itaru ^{[1
]}

Yagi, Kensuke ^{[2
]}

Miyamoto, Shinji ^{[1
]}

Shibata, Ikuya ^{[1
]}

机构：

[1] Osaka Univ, Res Ctr Environm Preservat, 2-4 Yamadaoka, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Grad Sch Engn, Div Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan

来源：

RSC ADVANCES | 2020年 / 10卷 / 10期

关键词：

CARBONYL-COMPOUNDS; TRANSFER HYDROGENATION; ALLYLIC INDIUM; RUTHENIUM; DIENES; HYDROHYDROXYALKYLATION; HYDRIDE; ALDEHYDES; CONSTRUCTION; CROTYLATION;

D O I：

10.1039/d0ra00853b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, in situ catalytically generated allylic indium from 1,3 dienes and InCl2H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C bonds, which could then be applied to many types of ketones. Other branched 1,3 dienes and vinyl cyclopropanes, could also be coupled with ketones in a reaction where CuH would not be applicable.

引用

页码：6030 / 6034

页数：5

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