Review-Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries: Promises and Challenges

被引:156
作者
Judez, Xabier [1 ]
Zhang, Heng [1 ]
Li, Chunmei [1 ]
Eshetu, Gebrekidan Gebresilassie [1 ]
Gonzalez-Marcos, Jose A. [2 ]
Armand, Michel [1 ]
Rodriguez-Martinez, Lide M. [1 ]
机构
[1] CIC Energigune, Parque Tecnol Alava, Minano 01510, Alava, Spain
[2] Univ Basque Country, Fac Sci & Technol, Dept Chem Engn, UPV EHU, Bilbao 48080, Spain
关键词
LI-S BATTERIES; COMPOSITE POLYMER ELECTROLYTES; ELECTROCHEMICAL PROPERTIES; PERFORMANCE IMPROVEMENT; CATHODE MATERIALS; BINDER MATERIALS; HIGH-CAPACITY; METAL ANODE; STATE; DISCHARGE;
D O I
10.1149/2.0041801jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
All-solid-state lithium-sulfur batteries (ASSLSBs) offer a means to enhance the energy density and safety of the state-of-art lithium-ion batteries (LIBs), due to their high gravimetric energy density, low cost and environmental benignancy. In this work, the status of the research advances and perspectives on several types of solid electrolytes (SEs) developed for ASSLSBs are reviewed. The promises and challenges of utilizing SEs are discussed taking into account both theoretical calculation and experimental results, in hope of shedding some lights on future design of high energy density, cost competitive, and safe Li-S batteries. (C) The Author(s) 2017. Published by ECS.
引用
收藏
页码:A6008 / A6016
页数:9
相关论文
共 117 条
[1]   A lithium-ion sulfur battery using a polymer, polysulfide-added membrane [J].
Agostini, Marco ;
Hassoun, Jusef .
SCIENTIFIC REPORTS, 2015, 5
[2]   A lithium-sulfur battery using a solid, glass-type P2S5-Li2S electrolyte [J].
Agostini, Marco ;
Aihara, Yuichi ;
Yamada, Takanobu ;
Scrosati, Bruno ;
Hassoun, Jusef .
SOLID STATE IONICS, 2013, 244 :48-51
[3]   Jeffamine® based polymers as highly conductive polymer electrolytes and cathode binder materials for battery application [J].
Aldalur, Itziar ;
Zhang, Heng ;
Piszcz, Michal ;
Oteo, Uxue ;
Rodriguez-Martinez, Lide M. ;
Shanmukaraj, Devaraj ;
Rojo, Teofilo ;
Armand, Michel .
JOURNAL OF POWER SOURCES, 2017, 347 :37-46
[4]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[5]   Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].
Aurbach, D .
JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218
[6]   On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries [J].
Aurbach, Doron ;
Pollak, Elad ;
Elazari, Ran ;
Salitra, Gregory ;
Kelley, C. Scordilis ;
Affinito, John .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (08) :A694-A702
[7]   Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction [J].
Bachman, John Christopher ;
Muy, Sokseiha ;
Grimaud, Alexis ;
Chang, Hao-Hsun ;
Pour, Nir ;
Lux, Simon F. ;
Paschos, Odysseas ;
Maglia, Filippo ;
Lupart, Saskia ;
Lamp, Peter ;
Giordano, Livia ;
Shao-Horn, Yang .
CHEMICAL REVIEWS, 2016, 116 (01) :140-162
[8]   Lithium-sulfur batteries-the solution is in the electrolyte, but is the electrolyte a solution? [J].
Barghamadi, Marzieh ;
Best, Adam S. ;
Bhatt, Anand I. ;
Hollenkamp, Anthony F. ;
Musameh, Mustafa ;
Rees, Robert J. ;
Ruether, Thomas .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (12) :3902-3920
[9]   Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries [J].
Cheng, Lei ;
Curtiss, Larry A. ;
Zavadil, Kevin R. ;
Gewirth, Andrew A. ;
Shao, Yuyan ;
Gallagher, Kevin G. .
ACS ENERGY LETTERS, 2016, 1 (03) :503-509
[10]   Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review [J].
Cheng, Xin-Bing ;
Zhang, Rui ;
Zhao, Chen-Zi ;
Zhang, Qiang .
CHEMICAL REVIEWS, 2017, 117 (15) :10403-10473