Organo lanthanide metal complexes for application as emitting layer in OLEDs

被引:4
作者
Priya, J. [1 ]
Sharma, S. K. [1 ]
机构
[1] Indian Sch Mines, Dept Appl Phys, Indian Inst Technol, Dhanbad 826004, Bihar, India
关键词
Compendex;
D O I
10.1007/s10854-017-7902-6
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The novel tetrakis beta-diketonate of lanthanum complexes M[La(acac)(4)] with a variety of cationic ligands, M = Li+, Na+ and K+ has been synthesized. The structural and optical characterizations of prepared complexes were carried out by FESEM, FTIR, UV-Vis and PL techniques. A transmittance at around 1600 cm(-1) was observed which corresponds to the ketonate group. The excitation spectra of the synthesized complexes show a broad peak in the range of 360-410 nm. Emission spectra were recorded by keeping excitation wavelength fixed at 390 nm. A good intensity emission peak due to O-2p -> La-5d transition of LaO8 was observed at 473 nm. The CIE chromaticity coordinates of all the complexes were observed in the blue region. It could be considered as promising phosphor for blue light emitting materials in OLEDs.
引用
收藏
页码:180 / 185
页数:6
相关论文
共 19 条
  • [1] Adati R.D., 2006, J ALLOY COMPD, V418, P1
  • [2] Synthesis of a functionalized europium complex and deposition of luminescent Langmuir-Blodgett (LB) films
    Adati, Renata D.
    Pavinatto, Felippe J.
    Monteiro, Jorge H. S. K.
    Davolos, Marian R.
    Jafelicci, Miguel, Jr.
    Oliveira, Osvaldo N., Jr.
    [J]. NEW JOURNAL OF CHEMISTRY, 2012, 36 (10) : 1978 - 1984
  • [3] OCTACOORDINATE CHELATES OF LANTHANIDES . 2 SERIES OF COMPOUNDS
    BAUER, H
    BLANC, J
    ROSS, DL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (23) : 5125 - +
  • [4] Synthesis, crystal structure, and luminescent properties of novel Eu3+ heterocyclic β-diketonate complexes with bidentate nitrogen donors
    Biju, S.
    Raj, D. B. Ambili
    Reddy, M. L. P.
    Kariuki, B. M.
    [J]. INORGANIC CHEMISTRY, 2006, 45 (26) : 10651 - 10660
  • [5] Binnemans K, 2005, HBK PHYS CHEM RARE, V35, P107, DOI 10.1016/S0168-1273(05)35003-3
  • [6] Tuning oxygen vacancy photoluminescence in monoclinic Y2WO6 by selectively occupying yttrium sites using lanthanum
    Ding, Bangfu
    Han, Chao
    Zheng, Lirong
    Zhang, Junying
    Wang, Rongming
    Tang, Zilong
    [J]. SCIENTIFIC REPORTS, 2015, 5
  • [7] Evans R.C., 2006, COORDIN CHEM REV, V250, P15
  • [8] Luminescence and photo-thermally stimulated defects creation processes in PbWO4 crystals doped with trivalent rare-earth ions
    Fabeni, P.
    Krasnikov, A.
    Kaerner, T.
    Laguta, V. V.
    Nikl, M.
    Pazzi, G. P.
    Zazubovich, S.
    [J]. JOURNAL OF LUMINESCENCE, 2013, 136 : 42 - 50
  • [9] Feng J., 2009, DALTON T, V7, P33
  • [10] Synthesis, characterization and spectroscopic investigation of new tetrakis(acetylacetonato)thulate(III) complexes containing alkaline metals as countercations
    Guedes, M. A.
    Paolini, T. B.
    Felinto, M. C. F. C.
    Kai, J.
    Nunes, L. A. O.
    Malta, O. L.
    Brito, H. F.
    [J]. JOURNAL OF LUMINESCENCE, 2011, 131 (01) : 99 - 103