Nano-aluminum powder mediated allylation of carbonyl compounds in aqueous media

被引：8

作者：

Yuan Shi-Zhen ^{[1
]}

Liu Jin ^{[1
]}

机构：

[1] Anhui Inst Architecture & Ind, Dept Mat Sci & Engn, Hefei 230022, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2008年 / 26卷 / 04期

关键词：

nano-aluminum; allylation reaction; aqueous media;

D O I：

10.1002/cjoc.200890150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new and effective Barbier-Grignard allylation of aldehydes or ketones has been carried out with nano-aluminum powder in aqueous 0.1 mol.L-1 NH4Cl (aq.) under an atmosphere of nitrogen. Aromatic carbonyl compounds gave homoallylic alcohols in good yields. The effectiveness of reaction was strongly influenced by the steric environment surrounding the carbonyl group. Aliphatic carbonyl compounds proceeded in low yields. The dominant stereoisomer was an erythro-isomer when an ortho-hydroxyl carbonyl compound was reacted under such a reaction condition.

引用

页码：804 / 806

页数：3

共 24 条

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