C,N,N-cyclometallated palladium(II) complexes: A step forward to luminescent metallomesogens

被引：58
|
作者：
Neve, F
Ghedini, M
Crispini, A
机构：
[1] Dipartimento di Chimica, Universitá della Calabria
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 21期
关键词：
D O I：
10.1039/cc9960002463
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclopalladation of 4'-functionalized 6'-phenyl-2,2'-bipyridine ligands (HL(n), n = 1-3) leads to [PdL(n)Cl] species as demonstrated by the crystal structure of [PdL(1)Cl]; thermotropic nematic mesomorphism is observed for HL(3) and [PdL(3)Cl]; the latter is also photoluminescent at 77 K.
引用
收藏
页码：2463 / 2464
页数：2
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