C,N,N-cyclometallated palladium(II) complexes: A step forward to luminescent metallomesogens

被引:59
作者
Neve, F
Ghedini, M
Crispini, A
机构
[1] Dipartimento di Chimica, Universitá della Calabria
关键词
D O I
10.1039/cc9960002463
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cyclopalladation of 4'-functionalized 6'-phenyl-2,2'-bipyridine ligands (HL(n), n = 1-3) leads to [PdL(n)Cl] species as demonstrated by the crystal structure of [PdL(1)Cl]; thermotropic nematic mesomorphism is observed for HL(3) and [PdL(3)Cl]; the latter is also photoluminescent at 77 K.
引用
收藏
页码:2463 / 2464
页数:2
相关论文
共 26 条
[1]   New tricks for an old ligand: Cyclometallated and didentate co-ordination of 2,2':6',2''-terpyridine to ruthenium(II) [J].
Bardwell, DA ;
Thompson, AMWC ;
Jeffery, JC ;
McCleverty, JA ;
Ward, MD .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (06) :873-878
[2]   MESOMORPHIC COMPLEXES OF RHENIUM(I) AND MANGANESE(I) [J].
BRUCE, DW ;
LIU, XH .
LIQUID CRYSTALS, 1995, 18 (01) :165-166
[3]  
BRUCE DW, 1992, INORG MATER, pCH8
[4]   Monomeric and dimeric ortho-metallated palladium(II)-imine systems as liquid crystals [J].
Buey, J ;
Espinet, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 507 (1-2) :137-145
[5]   STRUCTURE OF A C,N,N-CYCLOMETALATED PALLADIUM(II) COMPLEX OF 2-AMINO-4-PHENYLAMINO-6-(2-PYRIDYL)-1,3,5-TRIAZINE, AN ALPHA-DIIMINE LIGAND WITH DONOR-ACCEPTOR-DONOR HYDROGEN-BONDING CAPABILITY [J].
CHAN, CW ;
MINGOS, DMP ;
WHITE, AJP ;
WILLIAMS, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (14) :2469-2471
[6]   GOLD(III) PHOTOOXIDANTS - PHOTOPHYSICAL, PHOTOCHEMICAL PROPERTIES, AND CRYSTAL-STRUCTURE OF A LUMINESCENT CYCLOMETALATED GOLD(III) COMPLEX OF 2,9-DIPHENYL-1,10-PHENANTHROLINE [J].
CHAN, CW ;
WONG, WT ;
CHE, CM .
INORGANIC CHEMISTRY, 1994, 33 (07) :1266-1272
[7]  
CHAN CW, 1996, J CHEM SOC CHEM COMM, P81
[8]   Photoluminescent cyclometallated diplatinum(II,II) complexes: Photophysical properties and crystal structures of [PtL(PPh(3))]ClO4 and [Pt(2)L2(mu-dppm)][ClO4](2) (HL=6-phenyl-2,2'-bipyridine, dppm=Ph(2)PCH(2)PPh(2)) [J].
Cheung, TC ;
Cheung, KK ;
Peng, SM ;
Che, CM .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (08) :1645-1651
[9]   CYCLOPALLADATED AND CYCLOPLATINATED COMPLEXES OF 6-PHENYL-2,2'-BIPYRIDINE - PLATINUM PLATINUM INTERACTIONS IN THE SOLID-STATE [J].
CONSTABLE, EC ;
HENNEY, RPG ;
LEESE, TA ;
TOCHER, DA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) :513-515
[10]   CYCLOMETALLATION REACTIONS OF 6-PHENYL-2,2'-BIPYRIDINE - A POTENTIAL C,N,N-DONOR ANALOG OF 2,2'-6',2''-TERPYRIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS(6-PHENYL-2,2'-BIPYRIDINE)RUTHENIUM(II) [J].
CONSTABLE, EC ;
HENNEY, RPG ;
LEESE, TA ;
TOCHER, DA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :443-449