Hierarchical hollow structured lithium nickel cobalt manganese oxide microsphere synthesized by template-sacrificial route as high performance cathode for lithium ion batteries

被引：30

作者：

Xu, Chun-Liu ^{[1
]}

Xiang, Wei ^{[2
,3
]}

Wu, Zhen-Guo ^{[1
]}

Xu, Ya-Di ^{[1
]}

Li, Yong-Chun ^{[1
]}

Li, Hong-Tai ^{[1
]}

Xiao, Yao ^{[1
]}

Tan, Bo-Chuan ^{[4
]}

Guo, Xiao-Dong ^{[1
]}

Zhong, Ben-He ^{[1
]}

机构：

[1] Sichuan Univ, Sch Chem Engn, Chengdu 610065, Sichuan, Peoples R China

[2] Chengdu Univ Technol, Coll Mat & Chem & Chem Engn, Chengdu 610059, Sichuan, Peoples R China

[3] Ruyuan Hec Technol Corp, Postdoctoral Mobile Res Ctr, Ruyuan 512000, Guangdong, Peoples R China

[4] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2019年 / 777卷

基金：

中国国家自然科学基金;

关键词：

LiNi0.4Co0.2Mn0.4O2 cathode materials; Hierarchical structure; Hollow microsphere; Solvothermal; Template-sacrificial route; HIGH-RATE CAPABILITY; ELECTROCHEMICAL PERFORMANCE; DESIGNED SYNTHESIS; ANODE MATERIALS; LINI1/3CO1/3MN1/3O2; SPHERES; LI1.2NI0.2MN0.6O2; COPRECIPITATION; CRYSTALLINE; MNCO2O4;

D O I：

10.1016/j.jallcom.2018.10.380

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Materials with micro-nano hierarchical structure have shown excellent electrochemical performance for lithium ion batteries because of the favorable electron/ionic transportation provided by the unique geometrical structure. In this work, hierarchical LiNi0.4Co0.2Mn0.4O2 hollow microsphere is synthesized by a template-sacrificial route using porous CoMn2O4 template, which is prepared by pyrolysis of solvothermal synthesized Co1/3Mn2/3CO3 precursor. The influence of synthesis parameters in solvothermal reaction and high temperature calcining on the morphology of particles is systematically investigated. Benefiting from the desired micro-nano hierarchical porous hollow structure and well-ordered crystal structure, the LiNi0.4Co0.2Mn0.4O2 hollow microsphere exhibits excellent electrochemical performance and favorable Li+ extraction/insertion kinetics. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：434 / 442

页数：9

共 50 条

[41] Synthesis of pyrite/carbon shells on cobalt nanowires forming core/branch arrays as high-performance cathode for lithium ion batteries [J].

Cao, F. ;

Pan, G. X. ;

Chen, J. ;

Zhang, Y. J. ;

Xia, X. H. .

JOURNAL OF POWER SOURCES, 2016, 303 :35-40

[42] A new strategy to activate graphite oxide as a high-performance cathode material for lithium-ion batteries [J].

Xie, Yongqiang ;

Li, Wei ;

Hu, Guorong ;

Peng, Zhongdong ;

Cao, Yanbing ;

Du, Ke .

NEW JOURNAL OF CHEMISTRY, 2019, 43 (12) :4727-4733

[43] Reduced graphene oxide wrapped hollow molybdenum trioxide nanorod for high performance lithium-ion batteries [J].

Yang, Chenglong ;

Zhong, Xiongwu ;

Jiang, Yu ;

Yu, Yan .

CHINESE CHEMICAL LETTERS, 2017, 28 (12) :2231-2234

[44] Functionalization of graphene oxide with naphthalenediimide diamine for high-performance cathode materials of lithium-ion batteries [J].

Song, Yidan ;

Gao, Yuanrui ;

Rong, Hongren ;

Wen, Hao ;

Sha, Yanyong ;

Zhang, Hanping ;

Liu, Hong-Jiang ;

Liu, Qi .

SUSTAINABLE ENERGY & FUELS, 2018, 2 (04) :803-810

[45] Facile Fabrication of Hierarchical LiMnPO4 Microspheres for High-Performance Lithium-Ion Batteries Cathode [J].

Li, Junzhe ;

Luo, Shao-hua ;

Wang, Qing ;

Yan, Shengxue ;

Feng, Jian ;

Ding, Xueyong ;

He, Ping ;

Zong, Lingbo .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (02) :A118-A124

[46] Submicron lithium nickel manganese oxide spinel with long cycling stability and high rate performance prepared by a facile route [J].

Wang, Guoqing ;

Xie, Jian ;

Wu, Chunyang ;

Zhang, Shichao ;

Cao, Gaoshao ;

Zhao, Xinbing .

JOURNAL OF POWER SOURCES, 2014, 265 :118-124

[47] Self-sacrificing template based hollow carbon spheres/molybdenum dioxide nanocomposite for high-performance Lithium-ion batteries [J].

Rasheed, Tahir ;

Nabeel, Faran ;

Naveed, Ahmad ;

Majeed, Saadat ;

Sherazi, Tauqir A. .

MATERIALS TODAY COMMUNICATIONS, 2019, 21

[48] Hierarchical Fe3O4 microsphere/reduced graphene oxide composites as a capable anode for lithium-ion batteries with remarkable cycling performance [J].

Zhu, Kai ;

Zhang, Yu ;

Qiu, Hailong ;

Meng, Yuan ;

Gao, Yu ;

Meng, Xing ;

Gao, Zhongmin ;

Chen, Gang ;

Wei, Yingjin .

JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 675 :399-406

[49] A facile route to synthesize hollow Si-Ni3Sn2 nanospheres@ reduced graphene oxide nanocomposites for high performance lithium-ion batteries [J].

Wang, Ke ;

Huang, Ying ;

Yu, Meng ;

Qin, Xiulan .

JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 698 :547-554

[50] Machine-Learning Approach for Predicting the Discharging Capacities of Doped Lithium Nickel-Cobalt-Manganese Cathode Materials in Li-Ion Batteries [J].

Wang, Guanyu ;

Fearn, Tom ;

Wang, Tengyao ;

Choy, Kwang-Leong .

ACS CENTRAL SCIENCE, 2021, 7 (09) :1551-1560

← 1 2 3 4 5 →