Hierarchical hollow structured lithium nickel cobalt manganese oxide microsphere synthesized by template-sacrificial route as high performance cathode for lithium ion batteries

被引：30

作者：

Xu, Chun-Liu ^{[1
]}

Xiang, Wei ^{[2
,3
]}

Wu, Zhen-Guo ^{[1
]}

Xu, Ya-Di ^{[1
]}

Li, Yong-Chun ^{[1
]}

Li, Hong-Tai ^{[1
]}

Xiao, Yao ^{[1
]}

Tan, Bo-Chuan ^{[4
]}

Guo, Xiao-Dong ^{[1
]}

Zhong, Ben-He ^{[1
]}

机构：

[1] Sichuan Univ, Sch Chem Engn, Chengdu 610065, Sichuan, Peoples R China

[2] Chengdu Univ Technol, Coll Mat & Chem & Chem Engn, Chengdu 610059, Sichuan, Peoples R China

[3] Ruyuan Hec Technol Corp, Postdoctoral Mobile Res Ctr, Ruyuan 512000, Guangdong, Peoples R China

[4] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2019年 / 777卷

基金：

中国国家自然科学基金;

关键词：

LiNi0.4Co0.2Mn0.4O2 cathode materials; Hierarchical structure; Hollow microsphere; Solvothermal; Template-sacrificial route; HIGH-RATE CAPABILITY; ELECTROCHEMICAL PERFORMANCE; DESIGNED SYNTHESIS; ANODE MATERIALS; LINI1/3CO1/3MN1/3O2; SPHERES; LI1.2NI0.2MN0.6O2; COPRECIPITATION; CRYSTALLINE; MNCO2O4;

D O I：

10.1016/j.jallcom.2018.10.380

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Materials with micro-nano hierarchical structure have shown excellent electrochemical performance for lithium ion batteries because of the favorable electron/ionic transportation provided by the unique geometrical structure. In this work, hierarchical LiNi0.4Co0.2Mn0.4O2 hollow microsphere is synthesized by a template-sacrificial route using porous CoMn2O4 template, which is prepared by pyrolysis of solvothermal synthesized Co1/3Mn2/3CO3 precursor. The influence of synthesis parameters in solvothermal reaction and high temperature calcining on the morphology of particles is systematically investigated. Benefiting from the desired micro-nano hierarchical porous hollow structure and well-ordered crystal structure, the LiNi0.4Co0.2Mn0.4O2 hollow microsphere exhibits excellent electrochemical performance and favorable Li+ extraction/insertion kinetics. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：434 / 442

页数：9

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