Colorimetric and ratiometric fluorescent chemosensor for fluoride ion based on perylene diimide derivatives

被引：99

作者：

Chen, Zhi Jun

Wang, Li Min ^{[1
]}

Zou, Gang

Zhang, Liang

Zhang, Guan Jun

Cai, Xiao Fei

Teng, Ming Shuang

机构：

[1] E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China

来源：

DYES AND PIGMENTS | 2012年 / 94卷 / 03期

关键词：

PDIs; Naked-eye detection; Fluoride; Ratiometric; Chemosensor; Intermolecular proton transfer; ANION; SENSOR; PROBE;

D O I：

10.1016/j.dyepig.2012.01.024

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Based on a perylene diimide derivatives(PDIs) platform, AM-PDIs was rationally designed and synthesized as a new calorimetric and ratiometric fluorescent sensor for naked-eye detection of fluoride ion with high selectivity over other halide ions. Addition of fluoride ion to a dichloromethane(DCM) solution of AM-PDIs resulted in an obvious color change (from red to blackish green) because of a large red shift (151 nm) in absorption. The recognition mechanism was attributed to the intermolecular proton transfer between a hydrogen atom on the amide N position of sensor and the fluoride anion. The detection limit was calculated to be 0.14 mu M. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：410 / 415

页数：6

共 36 条

[11] Dynamic Behavior of a Fluorescent Probe, a Swallow-tailed Perylene Derivative for Detecting Hydroperoxides [J].