Continuous flow synthesis of porous materials

被引：42

作者：

Xin, Yu ^{[1
]}

Peng, Sheng ^{[1
]}

Chen, Junxing ^{[1
]}

Yang, Zujin ^{[1
]}

Zhang, Jianyong ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Mat Sci & Engn, MOE Lab Polymer Composite & Funct Mat, Guangzhou 510275, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2020年 / 31卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Porous materials; Continuous flow; Metal-organic frameworks; Zeolites; Covalent-organic frameworks; METAL-ORGANIC FRAMEWORKS; ULTRAFAST SYNTHESIS; MICROFLUIDIC APPROACH; ROOM-TEMPERATURE; PARTICLE-SIZE; ZEOLITE; MICROWAVE; CRYSTALS; REACTORS; DROPLET;

D O I：

10.1016/j.cclet.2019.09.054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous materials play an important role in chemical catalysis, separation and other industrial applications. High-efficiency preparation of porous materials has become an active research area. Conventional synthesis of porous materials has been dominated by one-pot solution processing conditions carried out by bulk mixing under conventional electric heating via hydrothermal, solvothermal or ionothermal reactions where high temperatures and pressures are the standard. Continuous flow synthesis has many key advantages in terms of efficient mass and heat transfer, precise control of residence times, improved opportunities for automation and feedback control of synthesis, scaling-up reactions and improved safety parameters compared to above mentioned conventional batch scale synthetic methods. In this review, continuous flow synthesis of various crystalline porous materials such as metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), porous organic cages and zeolites is discussed. Combination of microfluidic methods with other techniques are also shown including various heating ways and various methods of substrate adding. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：1448 / 1461

页数：14

共 87 条

[1] Microfluidic-based Synthesis of Covalent Organic Frameworks (COFs): A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface [J].

Abrishamkar, Afshin ;

Rodriguez-San-Miguel, David ;

Rodriguez Navarro, Jorge Andres ;

Rodriguez-Trujillo, Romen ;

Amabilino, David B. ;

Mas-Balleste, Ruben ;

Zamora, Felix ;

deMello, Andrew J. ;

Puigmarti-Luis, Josep .

JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 2017, (125)

[2] Electrosynthesis of Metal-Organic Frameworks: Challenges and Opportunities [J].

Al-Kutubi, Hanan ;

Gascon, Jorge ;

Sudhoelter, Ernst J. R. ;

Rassaei, Liza .

CHEMELECTROCHEM, 2015, 2 (04) :462-474

[3]

Ameloot R, 2011, NAT CHEM, V3, P382, DOI [10.1038/NCHEM.1026, 10.1038/nchem.1026]

[4] Continuous flow production of metal-organic frameworks [J].

Batten, Michael P. ;

Rubio-Martinez, Marta ;

Hadley, Trevor ;

Carey, Keri-Constanti ;

Lim, Kok-Seng ;

Polyzos, Anastasios ;

Hill, Matthew R. .

CURRENT OPINION IN CHEMICAL ENGINEERING, 2015, 8 :55-59

[5] Synthesis of metal-organic frameworks by continuous flow [J].

Bayliss, Peter A. ;

Ibarra, Ilich A. ;

Perez, Eduardo ;

Yang, Sihai ;

Tang, Chiu C. ;

Poliakoff, Martyn ;

Schroeder, Martin .

GREEN CHEMISTRY, 2014, 16 (08) :3796-3802

[6] Two-dimensional Covalent Organic Framework Thin Films Grown in Flow [J].

Bisbey, Ryan P. ;

DeBlase, Catherine R. ;

Smith, Brian J. ;

Dichtel, William R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (36) :11433-11436

[7] Dynamic flow synthesis of porous organic cages [J].

Briggs, Michael E. ;

Slater, Anna G. ;

Lunt, Neil ;

Jiang, Shan ;

Little, Marc A. ;

Greenaway, Rebecca L. ;

Hasell, Tom ;

Battilocchio, Claudio ;

Ley, Steven V. ;

Cooper, Andrew I. .

CHEMICAL COMMUNICATIONS, 2015, 51 (98) :17390-17393

[8] The assembly and use of continuous flow systems for chemical synthesis [J].

Britton, Joshua ;

Jamison, Timothy F. .

NATURE PROTOCOLS, 2017, 12 (11) :2423-2446

[9] Multi-step continuous-flow synthesis [J].

Britton, Joshua ;

Raston, Colin L. .

CHEMICAL SOCIETY REVIEWS, 2017, 46 (05) :1250-1271

[10] Immobilized Transition Metals as Catalysts for Cross-Couplings in Continuous Flow-A Critical Assessment of the Reaction Mechanism and Metal Leaching [J].

Cantillo, David ;

Kappe, C. Oliver .

CHEMCATCHEM, 2014, 6 (12) :3286-3305

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