Room-temperature multiferroic properties in 1.5LaFeO3-Bi4Ti3O12 thin films

被引:3
作者
Feng, Linyan [1 ,2 ]
Su, Jie [3 ]
Lu, Chaojing [1 ,2 ]
Li, Jin [1 ,2 ]
Luo, Li [1 ,2 ]
Liang, Kaili [1 ,2 ]
Yin, Hongmei [4 ]
Huang, Yineng [4 ]
机构
[1] Qingdao Univ, Coll Phys Sci, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Key Lab Photon Mat & Technol Univ Shandong, Qingdao 266071, Peoples R China
[3] Qingdao Univ, Sch Elect & Informat Engn, Qingdao 266071, Peoples R China
[4] Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condense, Yining 835000, Peoples R China
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
FERROELECTRIC PROPERTIES; HYSTERESIS DISPERSION; SUBSTITUTED BI4TI3O12; CERAMICS; SRBI2TA2O9; PEROVSKITE; SYSTEMS;
D O I
10.1007/s10854-017-8055-3
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Random-oriented 1.5LaFeO(3)-Bi4Ti3O12 thin films were fabricated on (111)Pt/Ti/SiO2/Si(100) substrates by a sol-gel method. Both X-ray diffraction and Raman spectroscopy characterizations confirm that the films have a single-phase Aurivillius structure with 4-5 successive perovskite blocks. The films exhibit room-temperature multiferroic properties with the remanent polarization 2P(r) similar to 27.20 mu C/cm(2) and saturated magnetization M-s similar to 4.28 emu/cm(3). Moreover, room-temperature magneto-dielectric effect with magneto-dielectric coefficient of similar to 1.03% was observed, which arises from the charge ordering of Fe2+ and Fe3+. Theoretical analysis of temperature-dependent dielectric spectrum and X-ray photoelectron spectroscopy data reveals a major contribution of charge ordering of Fe2+ and Fe3+ to the magneto-dielectric effect in 1.5LaFeO(3)-Bi4Ti3O12 thin films.
引用
收藏
页码:1473 / 1478
页数:6
相关论文
共 50 条
[1]   Effects of annealing temperature on the structures, ferroelectric and magnetic properties of Aurivillius Bi5Ti3FeO15 polycrystalline films [J].
Bai, W. ;
Zhu, J. Y. ;
Wang, J. L. ;
Lin, T. ;
Yang, J. ;
Meng, X. J. ;
Tang, X. D. ;
Zhu, Z. Q. ;
Chu, J. H. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2012, 324 (14) :2265-2270
[2]   Magnetic and ferroelectric properties of SmBi4Fe0.5Co0.5Ti3O15 compounds prepared with different synthesis methods [J].
Chen, Chun-Xia ;
Liu, Yu-Kuai ;
Zheng, Ren-Kui .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (11) :7562-7567
[3]   ELECTRICAL AND OPTICAL PROPERTIES OF FERROELECTRIC BI4TI3O12 SINGLE CRYSTALS [J].
CUMMINS, SE ;
CROSS, LE .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (05) :2268-&
[4]   Magnetocoupling and domain structure of BiFeO3/LaFeO3 heterostructures deposited on LaSrCoO3/Pt/TiO2/SiO2/Si (100) substrates by the soft chemical method [J].
Deus, R. C. ;
Goncalves, L. F. ;
Cavalcanti, C. C. ;
Rocha, L. S. R. ;
Longo, E. ;
Simoes, A. Z. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (12) :8630-8642
[5]   Magnetocapacitance of polycrystalline Bi5Ti3FeO15 prepared by sol-gel method [J].
Dong, X. W. ;
Wang, K. F. ;
Wan, J. G. ;
Zhu, J. S. ;
Liu, J. -M. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (09)
[6]   Preparation, Microstructure, and Ferroelectric Properties of Bi3.25La0.75Ti3-xMxO12 (M = Mo, W, Nb, V) Ceramics [J].
Du, Hongchu ;
Tang, Lijun ;
Kaskel, Stefan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (04) :1329-1339
[7]   Size effect and evidence of a size-driven phase transition in Bi4Ti3O12 nanocrystals [J].
Du, YL ;
Zhang, MS ;
Chen, Q ;
Yuan, ZR ;
Yin, Z ;
Zhang, QA .
SOLID STATE COMMUNICATIONS, 2002, 124 (03) :113-118
[8]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[9]   Dynamic hysteresis scaling of ferroelectric Pb0.9Ba0.1(Zr0.52Ti0.48)O3 thin films [J].
Guo, Y. Y. ;
Wei, T. ;
He, Q. Y. ;
Liu, J-M .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (48)
[10]   Ferroelectric properties and dynamic scaling of ⟨100⟩ oriented (K0.5Na0.5)NbO3 single crystals [J].
Gupta, Shashaank ;
Priya, Shashank .
APPLIED PHYSICS LETTERS, 2011, 98 (24)